A luminescent cerium metal-organic framework for the turn-on sensing of ascorbic acid.

Title A luminescent cerium metal-organic framework for the turn-on sensing of ascorbic acid.
Authors D. Yue; D. Zhao; J. Zhang; L. Zhang; K. Jiang; X. Zhang; Y. Cui; Y. Yang; B. Chen; G. Qian
Journal Chem Commun (Camb)
DOI 10.1039/c7cc05805e
Abstract

We report a cerium metal-organic framework (ZJU-136-Ce) for the turn-on fluorescence sensing of AA. The fluorescence enhancement is attributed to the specific redox reaction between AA and Ce(4+). The detection limit of AA reaches 7 nM, showing its potential for AA detection in the environmental industry and clinical medicine.

Citation D. Yue; D. Zhao; J. Zhang; L. Zhang; K. Jiang; X. Zhang; Y. Cui; Y. Yang; B. Chen; G. Qian.A luminescent cerium metal-organic framework for the turn-on sensing of ascorbic acid.. Chem Commun (Camb). 2017. doi:10.1039/c7cc05805e

Related Elements

Cerium

See more Cerium products. Cerium (atomic symbol: Ce, atomic number: 58) is a Block F, Group 3, Period 6 element with an atomic weight of 140.116. The number of electrons in each of cerium's shells is 2, 8, 18, 19, 9, 2 and its electron configuration is [Xe]4f2 6s2. Cerium Bohr ModelThe cerium atom has a radius of 182.5 pm and a Van der Waals radius of 235 pm. In its elemental form, cerium has a silvery white appearance. Cerium is the most abundant of the rare earth metals. It is characterized chemically by having two valence states, the +3 cerous and +4 ceric states. The ceric state is the only non-trivalent rare earth ion stable in aqueous solutions. Elemental CeriumIt is therefore strongly acidic and oxidizing, in addition to being moderately toxic.The cerous state closely resembles the other trivalent rare earths. Cerium is found in the minerals allanite, bastnasite, hydroxylbastnasite, monazite, rhabdophane, synchysite and zircon. Cerium was discovered by Martin Heinrich Klaproth, Jöns Jakob Berzelius, and Wilhelm Hisinger in 1803 and first isolated by Carl Gustaf Mosander in 1839. The element was named after the asteroid Ceres, which itself was named after the Roman god of agriculture.

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