A Water-Stable Dual-Channel Luminescence Sensor for UO2(2+) Ions Based on an Anionic Terbium(III) Metal-Organic Framework.

Title A Water-Stable Dual-Channel Luminescence Sensor for UO2(2+) Ions Based on an Anionic Terbium(III) Metal-Organic Framework.
Authors J. Ye; R.F. Bogale; Y. Shi; Y. Chen; X. Liu; S. Zhang; Y. Yang; J. Zhao; G. Ning
Journal Chemistry
DOI 10.1002/chem.201700713
Abstract

A stable 3D Tb(III) -based metal-organic framework [Tb(BPDC)2 ]?(CH3 )2 NH2 (DUT-101) was synthesized, and it is the first efficient dual-channel luminescence sensor for aqueous UO2(2+) ions. DUT-101 contains an anionic three-dimensional framework and protonated dimethylamine molecules embedded within the channels. The intense green emission of DUT-101 could be highly selectively and sensitively quenched by UO2(2+) ions even in the presence of other competing metal ions. A possible sensing mechanism was proposed based on both suppression of luminescence resonance energy transfer and enhancement of intermolecular electron transfer. Furthermore, visual green fluorescent test papers based on DUT-101 were fabricated and could be used to discriminate UO2(2+) ions among various metal ions.

Citation J. Ye; R.F. Bogale; Y. Shi; Y. Chen; X. Liu; S. Zhang; Y. Yang; J. Zhao; G. Ning.A Water-Stable Dual-Channel Luminescence Sensor for UO2(2+) Ions Based on an Anionic Terbium(III) Metal-Organic Framework.. Chemistry. 2017;23(32):76577662. doi:10.1002/chem.201700713

Related Elements

Terbium

65 Tb 158.925350000 Terbium

See more Terbium products. Terbium (atomic symbol: Tb, atomic number: 65) is a Block F, Group 3, Period 6 element with an atomic radius of 158.92535.Terbium Bohr Model The number of electrons in each of Terbium's shells is [2, 8, 18, 27, 8, 2] and its electron configuration is [Xe]4f9 6s2. The terbium atom has a radius of 177 pm and a Van der Waals radius of 221 pm.Terbium was discovered and first isolated by Carl Gustaf Mosander in 1842. In its elemental form, terbium is a silvery-white soft metal. Terbium is found in cerite, gadolinite, and monazite. It is not found in nature as a free element. Elemental TerbiumTerbium compounds are brightly fluorescent, and a majority of the world's terbium supply is used for creating green phosphors that enable trichromatic lighting technology. It is also frequently used as a dopant for crystalline solid-state devices and fuel cell materials. It is named after Ytterby, the town in Sweden where it was discovered.

Related Forms & Applications

Organometallics
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