SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 Flame
Pyr. Sol. 1 H250 Catches fire spontaneously if exposed to air.
Water-react. 2 H261 In contact with water releases flammable gas.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
F; Highly flammable
R15-17: Contact with water liberates extremely flammable gases. Spontaneously flammable in air.
Information concerning particular hazards for human and environment:
N/A
Hazards not otherwise classified
No data available.
Label elements
Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labeled according to the CLP regulation.
Hazard pictograms
GHS02
Signal word: Danger
Hazard statements
H250 Catches fire spontaneously if exposed to air.
H261 In contact with water releases flammable gas.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P222 Do not allow contact with air.
P231+P232 Handle under inert gas. Protect from moisture.
P370+P378 In case of fire: Use for extinction: Special powder for metal fires.
P422 Store contents under inert gas.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
B6 - Reactive flammable material
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 3
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment:
PBT: N/A.
vPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS No. / Substance Name:
7429-90-5 Aluminum
Identification number(s):
EC number: 231-072-3
Index number: 013-001-00-6
SECTION 4. FIRST AID MEASURES
Description of first aid measures
If inhaled:
In case of unconsciousness place patient stably in side position for transportation.
Supply fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
No information available.
Indication of any immediate medical attention and special treatment needed
No information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing media
Water
Special hazards arising from the substance or mixture
Spontaneously flammable in air.
If this product is involved in a fire, the following can be released:
Metal oxide fume
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions:
No special measures required.
Do not allow product to reach sewage system or any water course.
Do not allow to penetrate the ground/soil.
Methods and material for containment and cleanup:
Keep away from ignition sources.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Prevention of secondary hazards:
Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure adequate ventilation.
Information about protection against explosions and fires:
Substance/product is self ignitable.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Do not store together with acids.
Store away from oxidizing agents.
Store away from strong bases.
Store away from halogenated compounds.
Store away from air.
Store away from water/moisture.
Further information about storage conditions:
Store under dry inert gas.
This product is moisture sensitive.
This product is air sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Protect from humidity and water.
Specific end use(s)
No further relevant information available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
7429-90-5 Aluminum (100.0%)
PEL (USA) Long-term value: 15*; 15** mg/m³
*Total dust; ** Respirable fraction
REL (USA) Long-term value: 10* 5** mg/m³
*Total dust **Respirable fraction
TLV (USA) Long-term value: 1* mg/m³ as Al; *as respirable fraction
EL (Canada) Long-term value: 1.0 mg/m³ metal and insoluble compdounds, respirable
EV (Canada) Long-term value: 5 mg/m³ aluminium-containing (as aluminium)
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical general protective and industrial hygiene measures for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Breathing equipment:
Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
Suitability of gloves should be determined both by material and quality, the latter of which may vary by manufacturer.
Penetration time of glove material (in minutes): No data available.
Eye protection:
Safety glasses
Full face protection
Body protection:
Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Powder
Color: Silver gray
Odor: Odorless
Odor threshold: No data available.
pH: N/A.
Melting point/range: 660.4 °C (1221 °F)
Boiling point/range: 2519 °C (4566 °F)
Sublimation temperature / start: No data available.
Flash point: N/A
Flammability (solid, gas):
Contact with water liberates extremely flammable gases.
Ignition temperature: 400 °C (752 °F)
Decomposition temperature: No data available.
Auto igniting: Spontaneously flammable in air.
Danger of explosion: No data available.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure: N/A.
Density at 20 °C (68 °F): 2.7 g/cm³ (22.532 lbs/gal)
Relative density: No data available.
Vapor density: N/A.
Evaporation rate: N/A.
Solubility in Water (H2O):
Contact with water releases flammable gases
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: N/A.
Kinematic: N/A.
Other information
No information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
In contact with water releases flammable gases which may ignite spontaneously.
Catches fire spontaneously if exposed to air.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Spontaneously flammable in air.
Contact with water releases flammable gases
Conditions to avoid
No information available.
Incompatible materials:
Acids
Air
Oxidizing agents
Bases
Halocarbons
Water/moisture
Hazardous decomposition products:
Metal oxide fume
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity: N/A
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: N/A
Carcinogenicity:
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in terms of its carcinogenicity in humans and/or animals.
Reproductive toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure: N/A
Specific target organ system toxicity - single exposure: N/A
Aspiration hazard: N/A
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No information available.
Persistence and degradability:
No information available.
Bioaccumulative potential:
No information available.
Mobility in soil:
No information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without official permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage system.
Avoid transfer into the environment.
Results of PBT and vPvB assessment:
PBT: N/A.
vPvB: N/A.
Other adverse effects
No further relevant information available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation:
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA
UN1396
UN proper shipping name
DOT
Aluminum powder, uncoated
IMDG, IATA
ALUMINIUM POWDER, UNCOATED
Transport hazard class(es)
DOT
Class
4.3 Substances which, in contact with water, emit flammable gases.
Label
4.3
Class
4.3 (W2) Substances which, in contact with water, emit flammable gases
Label
4.3
IMDG, IATA
Class
4.3 Substances which, in contact with water, emit flammable gases.
Label
4.3
Packing group
DOT, IMDG, IATA
II
Environmental hazards:
N/A.
Special precautions for user
Warning: Substances which, in contact with water, emit flammable gases
EMS Number:
F-G,S-O
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN1396, Aluminum powder, uncoated, 4.3, II
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
7429-90-5 Aluminum
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to Know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
REACH - Pre-registered substances
Substance is listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.