SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
Hazards not otherwise classified No data available
GHS label elements, including precautionary statements
Hazard pictograms
GHS07
Signal word Warning
Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
Precautionary statements
P273 Avoid release to the environment.
WHMIS classification Not controlled
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 1
Flammability = 1
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
CAS No. / Substance Name:
2155-74-0 Antimony(III) n-butoxide
Identification number(s):
EC number: 218-456-6
Index number: 051-003-00-9
SECTION 4. FIRST AID MEASURES
Description of first aid measures
If inhaled:
Supply patient with fresh air. If not breathing, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
In case of skin contact:
Immediately wash with soap and water; rinse thoroughly.
Seek immediate medical advice.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed:
No data available
Indication of any immediate medical attention and special treatment needed:
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents Carbon dioxide, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
Contact with water releases flammable gases
If this product is involved in a fire, the following can be released:
Toxic metal oxide fume
Carbon monoxide and carbon dioxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow material to be released to the environment without official permits.
Methods and materials for containment and cleanup:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: No special measures required.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Information about protection against explosions and fires: No data available
Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Store away from water/moisture.
Further information about storage conditions:
Store under dry inert gas.
This product is moisture sensitive.
Keep container tightly sealed.
Store in cool, dry conditions in well-sealed containers.
Protect from humidity and water.
Specific end use(s) No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
Antimony and antimony compounds
mg/m3
ACGIH TLV 0.5
Austria MAK 0.5
Belgium TWA 0.5
Denmark TWA 0.5
Finland TWA 0.5
France VME 0.5
Germany MAK 0.5 (total dust)
Hungary TWA 0.5-STEL
Japan OEL 0.1; 2B Carcinogen
Korea TLV 0.5
Netherlands MAC-TGG 0.5
Norway TWA 0.5
Poland TWA 0.5; 1.5-STEL
Russia TWA 0.2; 0.5-STEL
Sweden NGV 0.5
Switzerland MAK-W 0.5
United Nations TWA 0.5
USA PEL 0.5
2155-74-0 Antimony(III) n-butoxide (100.0%)
PEL (USA) Long-term value: 0.5 mg/m3
as Sb
Additional information: No data
Exposure controls
Personal protective equipment
Follow typical protective and hygienic practices for handling chemicals.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use suitable respirator when high concentrations are present.
Protection of hands:
Impervious gloves
Inspect gloves prior to use.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Penetration time of glove material (in minutes) No data available
Eye protection: Safety glasses
Body protection: Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Liquid
Color: Colorless
Odor: No data available
Odor threshold: No data available.
pH: No data available.
Melting point/Melting range: No data available
Boiling point/Boiling range: 133-135 °C (271-275 °F) (0.4mm Hg)
Sublimation temperature / start: No data available
Flash point: > 110 °C (> 230 °F)
Flammability (solid, gas) No data available.
Ignition temperature: No data available
Decomposition temperature: No data available
Autoignition: No data available.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: No data available
Density at 20 °C (68 °F): 1.264 g/cm3 (10.548 lbs/gal)
Relative density No data available.
Vapor density No data available.
Evaporation rate No data available.
Solubility in / Miscibility with
Water: Reacts
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Other information No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity No data available
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions No dangerous reactions known
Conditions to avoid No data available
Incompatible materials:
Oxidizing agents
Water/moisture
Hazardous decomposition products:
Toxic metal oxide fume
Carbon monoxide and carbon dioxide
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
Harmful if inhaled.
Harmful if swallowed.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity: No effects known.
Carcinogenicity: No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
Reproductive toxicity: No effects known.
Specific target organ system toxicity - repeated exposure: No effects known.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity:
Antimony compounds may cause metallic taste, gastrointestinal disturbances, vomiting, diarrhea, dizziness and systemic poisoning. Chronic exposure may cause
liver and kidney damage. Dermatitis and eczematous skin eruptions may result from skin contact.
Subacute to chronic toxicity: No effects known.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity: No data available
Persistence and degradability No data available
Bioaccumulative potential No data available
Mobility in soil No data available
Ecotoxical effects:
Remark: Toxic for aquatic organisms
Additional ecological information:
Do not allow product to reach groundwater, water courses, or sewage systems.
Toxic for aquatic organisms
Do not allow material to be released to the environment without official permits.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic to aquatic life.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT: N/A
vPvB: N/A
Other adverse effects No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation Consult official regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA UN3082
UN proper shipping name
DOT Environmentally hazardous substances, liquid, n.o.s. (Antimony(III) n-butoxide)
IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Antimony(III)
n-butoxide), MARINE POLLUTANT
IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Antimony(III)
n-butoxide)
Transport hazard class(es)
DOT, IMDG, IATA
Class 9 Miscellaneous dangerous substances and articles.
Label 9
Class 9 (M6) Miscellaneous dangerous substances and articles
Label 9
Packing group
DOT, IMDG, IATA III
Environmental hazards:
Marine pollutant (IMDG): Symbol (fish and tree)
Special marking (ADR): Symbol (fish and tree)
Special marking (IATA): Symbol (fish and tree)
Special precautions for user Warning: Miscellaneous dangerous substances and articles
EMS Number: F-A,S-F
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code N/A
Transport/Additional information:
DOT
Marine Pollutant (DOT): No
Remarks: Special marking with the symbol (fish and tree).
UN "Model Regulation": UN3082, Environmentally hazardous substances, liquid, n.o.s. (Antimony(III) n-butoxide), 9, III
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements, including precautionary statements
Hazard pictograms
GHS07
Signal word Warning
Hazard statements
H302+H332 Harmful if swallowed or if inhaled.
Precautionary statements
P273 Avoid release to the environment.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings)
2155-74-0 Antimony(III) n-butoxide
California Proposition 65
Prop 65 - Chemicals known to cause cancer Substance is not listed.
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
This product contains antimony and is subject to the reporting requirements of section 313 of the Emergency Planning and Community Right to know Act of 1986 and 40CFR372.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006. Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use) Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
