Benzoate Anions-Intercalated Layered Cobalt Hydroxide Nanoarray: An Efficient Electrocatalyst for Oxygen Evolution Reaction.

Title Benzoate Anions-Intercalated Layered Cobalt Hydroxide Nanoarray: An Efficient Electrocatalyst for Oxygen Evolution Reaction.
Authors X. Sun
Journal ChemSusChem
DOI 10.1002/cssc.201701358
Abstract

Efficient oxygen evolution reaction (OER) catalysts are highly desired to improve the overall efficiency of electrochemical water splitting. In this communication, we develop a benzoate anions-intercalated layered cobalt hydroxide nanobelt array on nickel foam (benzoate-Co(OH)2/NF) via a one-pot hydrothermal process. As a three-dimensional electrode, benzoate-Co(OH)2/NF with an expanded interlayer spacing (14.72 Å) drives a high OER catalytic current density of 50 mA cm-2 at an overpotential of 291 mV, outperforming its carbonate anions-intercalated counterpart with a lower interlayer spacing of 8.81 Å (337 mV overpotential at 50 mA cm-2). Moreover, this benzoate-Co(OH)2/NF can maintain its catalytic activity for 21 h.

Citation X. Sun.Benzoate Anions-Intercalated Layered Cobalt Hydroxide Nanoarray: An Efficient Electrocatalyst for Oxygen Evolution Reaction.. ChemSusChem. 2017. doi:10.1002/cssc.201701358

Related Elements

Cobalt

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar]3d7 4s2. The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit.

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