SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Skin irritation (Category 2), H315
Eye irritation (Category 2A), H319
Reproductive toxicity (Category 1B), H360
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Signal word: Danger
Hazard statement(s):
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H360 May damage fertility or the unborn child.
Precautionary statement(s):
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
P321 Specific treatment (see supplemental first aid instructions on this label).
P332 + P313 If skin irritation occurs: Get medical advice/ attention.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P362 Take off contaminated clothing and wash before reuse.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/ container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC) or not covered by GHS - none
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Formula: 11B2O3
Molecular weight: 70.02 g/mol
CAS-No: 77704-22-4
SECTION 4. FIRST AID MEASURES
General advice:
Move out of dangerous area.Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled:
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact:
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact:
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed:
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed:
The most important known symptoms and effects are described in the labelling
Indication of any immediate medical attention and special treatment needed:
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media:
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture:
Borane/boron oxides
Advice for firefighters:
Wear self-contained breathing apparatus for firefighting if necessary.
Further information:
No data available
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
For personal protection see section 8.
Environmental precautions:
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up:
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.
SECTION 7. HANDLING AND STORAGE
Precautions for safe handling:
Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities:
Keep container tightly closed in a dry and well-ventilated place.
Storage class (TRGS 510): 6.1D: Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects.
Specific end use(s):
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters:
Contains no substances with occupational exposure limit values.
Exposure controls
Appropriate engineering controls:
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection:
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection:
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection:
Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection:
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure:
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
nformation on basic physical and chemical properties
Appearance Form: solid
Odour No data available
Odour Threshold No data available
pH No data available
Melting point/freezing point
Melting point/range: 450 °C (842 °F) - lit.
Initial boiling point and boiling range:
No data available
Flash point Not applicable
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper/lower flammability or explosive limits
No data available
Vapour pressure No data available
Vapour density No data available
Relative density 2.474 g/mL at 25 °C (77 °F)
Water solubility No data available
Partition coefficient: noctanol/water: No data available
Auto-ignition temperature: No data available
Decomposition temperature: No data available
Viscosity No data available
Explosive properties No data available
Oxidizing properties No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity: No data available
Chemical stability:
Stable under recommended storage conditions.
Possibility of hazardous reactions:
No data available
Conditions to avoid:
Avoid moisture.
Incompatible materials: acids, Hydroxides
Hazardous decomposition products:
Hazardous decomposition products formed under fire conditions. - Borane/boron oxides
Other decomposition products - No data available
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity:
No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is on OSHA’s
list of regulated carcinogens.
Reproductive toxicity:
May damage fertility. May damage the unborn child.
Presumed human reproductive toxicant
Specific target organ toxicity - single exposure:
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure:
No data available
Aspiration hazard:
No data available
Additional Information:
RTECS: Not available
SECTION 12. ECOLOGICAL INFORMATION
Toxicity: No data available
Persistence and degradability:
No data available
Bioaccumulative potential:
No data available
Mobility in soil:
No data available(Boron-11B oxide)
Results of PBT and vPvB assessment:
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods:
Product:
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging:
Dispose of as unused product.
SECTION 14. TRANSPORT INFORMATION
DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
SECTION 15. REGULATORY INFORMATION
SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Acute Health Hazard, Chronic Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Boron-11B oxide
CAS-No. 77704-22-4
New Jersey Right To Know Components
Boron-11B oxide
CAS-No. 77704-22-4
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
