C4-Ferrocenylsilyl-bridged and -substituted N-heterocyclic carbenes: complexation of germanium chloride.

Title C4-Ferrocenylsilyl-bridged and -substituted N-heterocyclic carbenes: complexation of germanium chloride.
Authors Y. Wang; H.P. Hickox; P. Wei; G.H. Robinson
Journal Dalton Trans
DOI 10.1039/c7dt00066a
Abstract

While the 1?:?1 reaction of C4-trichlorosilyl-functionalized N-heterocyclic carbene (NHC) (2) with [(?(5)-C5H4Li)2Fe]3[TMEDA]2 (3) gives C4-sila[1]ferrocenophane-substituted NHC (4), C4-ferrocenylsilyl-bridged bis-NHC (6) is synthesized by combining 3 with C4-chlorodimethylsilyl-functionalized NHC (5) in a 1?:?2 ratio, (compound 5 is prepared by reaction of the anionic N-heterocyclic dicarbene (NHDC) [:C{[N(2,6-Pr(i)2C6H3)]2CHCLi}]n (1) with Me2SiCl2). In addition, ligand 4- and 6-based GeCl2 complexes (7 and 8) are also synthesized. Compounds 4-8 have been characterized by (1)H, (13)C, and (29)Si NMR spectroscopy and single crystal X-ray diffraction.

Citation Y. Wang; H.P. Hickox; P. Wei; G.H. Robinson.C4-Ferrocenylsilyl-bridged and -substituted N-heterocyclic carbenes: complexation of germanium chloride.. Dalton Trans. 2017. doi:10.1039/c7dt00066a

Related Elements

Germanium

See more Germanium products. Germanium (atomic symbol: Ge, atomic number: 32) is a Block P, Group 14, Period 4 element with an atomic weight of 72.63. Germanium Bohr ModelThe number of electrons in each of germanium's shells is 2, 8, 18, 4 and its electron configuration is [Ar] 3d10 4s2 4p2. The germanium atom has a radius of 122.5 pm and a Van der Waals radius of 211 pm. Germanium was first discovered by Clemens Winkler in 1886. In its elemental form, germanium is a brittle grayish white semi-metallic element. Germanium is too reactive to be found naturally on Earth in its native state. High Purity (99.999%) Germanium (Ge) MetalIt is commercially obtained from zinc ores and certain coals. It is also found in argyrodite and germanite. It is used extensively as a semiconductor in transitors, solar cells, and optical materials. Other applications include acting an alloying agent, as a phosphor in fluorescent lamps, and as a catalyst. The name Germanium originates from the Latin word "Germania" meaning "Germany."

Chlorine

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s23p5. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. Chlorine ModelIn its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. It has the third highest electronegativity and the highest electron affinity of all elements, making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

Related Forms & Applications