SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS02 Flame
Flam. Sol. 2 H228 Flammable solid.
GHS06 Skull and crossbones
Acute Tox. 2 H330 Fatal if inhaled.
GHS08 Health hazard
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1B H350 May cause cancer.
Repr. 2 H361 Suspected of damaging fertility or the unborn child.
STOT RE 1 H372 Causes damage to the lung, the kidneys, the reproductive system and the blood through prolonged or repeated exposure. Route of exposure: Oral.
Hazards not otherwise classified: None.
Label elements
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms

GHS02 GHS06 GHS08
Signal word Danger
Hazard statements
H228 Flammable solid.
H330 Fatal if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to the lung, the kidneys, the reproductive system and the blood through prolonged or repeated exposure. Route of exposure: Oral.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P284 [In case of inadequate ventilation] wear respiratory protection.
P320 Specific treatment is urgent (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
B4 - Flammable solid
D1A - Very toxic material causing immediate and serious toxic effects
D2A - Very toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 3
Flammability = 3
Physical Hazard = 1
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Substances
CAS# Description:
7440-43-9 Cadmium
Concentration: ≤100%
Identification number(s):
EC number: 231-152-8

SECTION 4. FIRST AID MEASURES

Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Seek medical treatment.
Information for doctor
Most important symptoms and effects, both acute and delayed
Fatal if inhaled.
May cause cancer.
Suspected of damaging fertility or the unborn child.
Causes damage to the lung, the kidneys, the reproductive system and the blood through prolonged or repeated exposure. Route of exposure: Oral.
Indication of any immediate medical attention and special treatment needed No further relevant information available.

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing agents Special powder for metal fires. Do not use water.
For safety reasons unsuitable extinguishing agents Water
Special hazards arising from the substance or mixture
If this product is involved in a fire, the following can be released:
Cadmium oxide
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Keep away from ignition sources
Environmental precautions: Do not allow product to reach sewage system or any water course.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards: Keep away from ignition sources.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1: 0.10 mg/m3
PAC-2: 0.76 mg/m3
PAC-3: 4.7 mg/m3

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires: Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: No information known.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Specific end use(s) No further relevant information available.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
7440-43-9 Cadmium (100.0%)
PEL (USA) Long-term value: 0.005 mg/m³
as Cd; see 29 CFR 1910.1027
REL (USA) See Pocket Guide App. A
TLV (USA) Long-term value: 0.01 0.002* mg/m³
as Cd; *respirable fraction; BEI
EL (Canada) Long-term value: 0.01 0.002* mg/m³
as Cd; ACGIH A2, IARC 1; *respirable
EV (Canada) Long-term value: 0.01 0.002* mg/m³
*respirable
Ingredients with biological limit values:
7440-43-9 Cadmium (100.0%)
BEI (USA) 5 μg/g creatinine
Medium: urine
Time: not critical
Parameter: Cadmium (background)
5 μg/L
Medium: blood
Time: not critical
Parameter: Cadmium (background)
Additional information: No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Maintain an ergonomically appropriate working environment.
Breathing equipment: Use self-contained respiratory protective device in emergency situations.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls. Risk assessment should be performed to determine if airpurifying
respirators are appropriate. Only use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary from manufacturer to manufacturer.
Material of gloves Nitrile rubber, NBR
Penetration time of glove material (in minutes) 480
Glove thickness: 0.11 mm
Eye protection: Safety glasses with side shields / NIOSH (US) or EN 166(EU)
Body protection: Protective work clothing.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
General Information
Appearance:
Form: Powder
Odor: Not determined
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: 321.1 °C (610 °F)
Boiling point/Boiling range: 765 °C (1409 °F)
Sublimation temperature / start: Not determined
Flammability (solid, gaseous) Highly flammable.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Not determined.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure at 180 °C (356 °F): 0.00013 hPa
Density at 20 °C (68 °F): 8.65 g/cm³ (72.184 lbs/gal)
Bulk density at 20 °C (68 °F): 2700 kg/m³
Relative density Not determined.
Vapor density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
Water: Not determined
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information No further relevant information available.

SECTION 10. STABILITY AND REACTIVITY

Reactivity No information known.
Chemical stability Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided: Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions No dangerous reactions known
Conditions to avoid No further relevant information available.
Incompatible materials: No information known.
Hazardous decomposition products: Cadmium oxide

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity:
Fatal if inhaled.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this substance.
LD/LC50 values that are relevant for classification: No data
Skin irritation or corrosion: May cause irritation
Eye irritation or corrosion: May cause irritation
Sensitization: No sensitizing effects known.
Germ cell mutagenicity:
Suspected of causing genetic defects.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains mutation data for this substance.
Carcinogenicity:
May cause cancer.
IARC-1: Carcinogenic to humans: sufficient evidence of carcinogenicity.
EPA-B1: Probable human carcinogen, limited evidence of carcinogenicity from epidemiologic studies.
Carcinogen as defined by OSHA.
ACGIH A2: Suspected human carcinogen: Agent is carcinogenic in experimental animals at dose levels, by route(s) of administration, at site(s), of histologic type(s),
or by mechanism(s) considered relevant to worker exposure. Available epidemiologic studies are conflicting or insufficient to confirm an increased risk of cancer in
exposed humans.
NTP-K: Known to be carcinogenic: sufficient evidence from human studies.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains tumorigenic and/or carcinogenic and/or neoplastic data for this substance.
Reproductive toxicity:
Suspected of damaging fertility or the unborn child.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains reproductive data for this substance.
Specific target organ system toxicity - repeated exposure:
Causes damage to the lung, the kidneys, the reproductive system and the blood through prolonged or repeated exposure. Route of exposure: Oral.
Specific target organ system toxicity - single exposure: No effects known.
Aspiration hazard: No effects known.
Subacute to chronic toxicity: The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for this substance.
Additional toxicological information: To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Ecotoxical effects:
Remark: Very toxic for aquatic organisms
Additional ecological information:
General notes:
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
May cause long lasting harmful effects to aquatic life.
Avoid transfer into the environment.
Very toxic for aquatic organisms
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Recommendation Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.

SECTION 14. TRANSPORT INFORMATION

UN-Number
DOT, IMDG, IATA UN3179
UN proper shipping name
DOT Flammable solid, toxic, inorganic, n.o.s. (Cadmium powder)
ADR 3179 Flammable solid, toxic, inorganic, n.o.s. (Cadmium powder)
IMDG, IATA FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. (Cadmium powder)
Transport hazard class(es)
DOT
Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives
Label 4.1, 6.1
ADR
Class 4.1 (FT2) Flammable solids, self-reactive substances and solid desensitized explosives
Label 4.1+6.1
IMDG
Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives
Label 4.1/6.1
IATA
Class 4.1 Flammable solids, self-reactive substances and solid desensitized explosives
Label 4.1 (6.1)
Packing group
DOT, ADR, IMDG, IATA II
Environmental hazards: Not applicable.
Special precautions for user Warning: Flammable solids, self-reactive substances and solid desensitized explosives
EMS Number: F-A,S-G
Stowage Category B
Stowage Code SW2 Clear of living quarters.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable.
Transport/Additional information:
DOT
Quantity limitations On passenger aircraft/rail: 15 kg
On cargo aircraft only: 50 kg
Hazardous substance: 10 lbs, 4.54 kg
Marine Pollutant (DOT): No
IMDG
Limited quantities (LQ) 1 kg
Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 g
Maximum net quantity per outer packaging: 500 g
UN "Model Regulation": UN 3179 FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. (CADMIUM POWDER), 4.1 (6.1), II

SECTION 15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS02 GHS06 GHS08
Signal word Danger
Hazard statements
H228 Flammable solid.
H330 Fatal if inhaled.
H341 Suspected of causing genetic defects.
H350 May cause cancer.
H361 Suspected of damaging fertility or the unborn child.
H372 Causes damage to the lung, the kidneys, the reproductive system and the blood through prolonged or repeated exposure. Route of exposure: Oral.
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P260 Do not breathe dust/fume/gas/mist/vapors/spray.
P284 [In case of inadequate ventilation] wear respiratory protection.
P320 Specific treatment is urgent (see on this label).
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Domestic Substances List (DSL).
SARA Section 313 (specific toxic chemical listings)
7440-43-9 Cadmium
California Proposition 65
Prop 65 - Chemicals known to cause cancer
7440-43-9 Cadmium
Prop 65 - Developmental toxicity Substance is not listed.
Prop 65 - Developmental toxicity, female Substance is not listed.
Prop 65 - Developmental toxicity, male
7440-43-9 Cadmium
Information about limitation of use:
Workers are not allowed to be exposed to this hazardous material. Exceptions can be made by the authorities in certain cases.
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
This substance is included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH).
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the
market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorisation for use)
Substance is not listed.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.