Calcium Hydride Reactivity: Formation of an Anionic N-Heterocyclic Olefin Ligand.

Title Calcium Hydride Reactivity: Formation of an Anionic N-Heterocyclic Olefin Ligand.
Authors A. Causero; H. Elsen; J. Pahl; S. Harder
Journal Angew Chem Int Ed Engl
DOI 10.1002/anie.201703037
Abstract

An anionic N-heterocyclic olefin ligand was serendipitously obtained by reaction of an amidinate calcium hydride complex with 1,3-dimethyl-2-methyleneimidazole (NHO). Instead of anticipated addition to the polarized C=CH2 bond to form an unstabilized alkylcalcium complex, deprotonation of the NHO ligand in the backbone was observed. Preference for deprotonation versus addition is explained by loss of aromaticity in the latter conversion. Theoretical calculations demonstrate the substantially increased ylidic character of this anionic NHO ligand which, like N-heterocyclic dicarbenes, shows strong bifunctional coordination.

Citation A. Causero; H. Elsen; J. Pahl; S. Harder.Calcium Hydride Reactivity: Formation of an Anionic N-Heterocyclic Olefin Ligand.. Angew Chem Int Ed Engl. 2017;56(24):69066910. doi:10.1002/anie.201703037

Related Elements

Calcium

See more Calcium products. Calcium (atomic symbol: Ca, atomic number: 20) is a Block S, Group 2, Period 4 element with an atomic weight of 40.078. The number of electrons in each of Calcium's shells is [2, 8, 8, 2] and its electron configuration is [Ar]4s2. Calcium Bohr ModelThe calcium atom has a radius of 197 pm and a Van der Waals radius of 231 pm. Calcium was discovered and first isolated by Sir Humphrey Davy in 1808. It is the fifth most abundant element in the earth's crust and can be found in minerals such as dolomite, gypsum, plagioclases, amphiboles, pyroxenes and garnets. In its elemental form, calcium has a dull gray-silver appearance. Calcium is a reactive, soft metal that is a member of the alkaline earth elements. Elemental CalciumIt frequently serves as an alloying agent for other metals like aluminum and beryllium, and industrial materials like cement and mortar are composed of calcium compounds like calcium carbonate. It is also an biologically essential substance found in teeth, bones, and shells. The name "calcium" originates from the Latin word "calics," meaning lime.

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