SECTION 2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Oxidizing solids Category 2
Skin Corrosion/Irritation Category 1 B
Serious Eye Damage/Eye Irritation Category 1
Specific target organ toxicity (single exposure) Category 3
Target Organs - Respiratory system.
Signal Word
Danger
Hazard Statements
May intensify fire; oxidizer
Causes severe skin burns and eye damage
May cause respiratory irritation
Precautionary Statements
Prevention
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Use only outdoors or in a well-ventilated area
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep/Store away from clothing/ other combustible materials
Take any precaution to avoid mixing with combustibles
Response
Immediately call a POISON CENTER or doctor/physician
Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Ingestion
IF SWALLOWED: Rinse mouth. DO NOT induce vomiting
Fire
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage
Store locked up
Store in a well-ventilated place. Keep container tightly closed
Disposal
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC)
None identified
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component / CAS-No / Weight %:
Calcium peroxide / 1305-79-9 / <=100
SECTION 4. FIRST AID MEASURES
General Advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is
required.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Immediate medical attention is required. Keep eye wide open while rinsing.
Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated
clothes and shoes. Call a physician immediately.
Inhalation Remove to fresh air. If not breathing, give artificial respiration. Call a physician or poison
control center immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a
one-way valve or other proper respiratory medical device.
Ingestion Immediate medical attention is required. Do NOT induce vomiting. Drink plenty of water.
Never give anything by mouth to an unconscious person.
Most important symptoms and
effects
Causes burns by all exposure routes. Product is a corrosive material. Use of gastric
lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should
be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue
and danger of perforation
Notes to Physician Treat symptomatically
SECTION 5. FIREFIGHTING MEASURES
Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam.
Unsuitable Extinguishing Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature No information available
Explosion Limits
Upper No data available
Lower No data available
Oxidizing Properties Oxidizer
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical
The product causes burns of eyes, skin and mucous membranes. Oxidizer: Contact with combustible/organic material may cause
fire. May ignite combustibles (wood paper, oil, clothing, etc.).
Hazardous Combustion Products
None known.
Protective Equipment and Precautions for Firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear. Thermal decomposition can lead to release of irritating gases and vapors.
NFPA
Health
3
Flammability
0
Instability
0
Physical hazards
- OX
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions Use personal protective equipment as required. Evacuate personnel to safe areas. Avoid
contact with skin, eyes or clothing.
Environmental Precautions Should not be released into the environment. Do not allow material to contaminate ground
water system. See Section 12 for additional Ecological Information.
Methods for Containment and Clean Up
Sweep up and shovel into suitable containers for disposal. Avoid dust formation. Soak up
with inert absorbent material. Keep in suitable, clo
SECTION 7. HANDLING AND STORAGE
Handling
Wear personal protective equipment/face protection. Do not get in eyes, on skin, or on
clothing. Use only under a chemical fume hood. Do not breathe dust. Do not ingest. If
swallowed then seek immediate medical assistance. Keep away from clothing and other combustible materials.
Storage
Corrosives area. Keep containers tightly closed in a dry, cool and well-ventilated place. Do
not store near combustible materials.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
This product does not contain any hazardous materials with occupational exposure
limitsestablished by the region specific regulatory bodies.
Engineering Measures Ensure that eyewash stations and safety showers are close to the workstation location.
Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by
OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard
EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State Solid
Appearance Yellow
Odor Odorless
Odor Threshold No information available
pH No information available
Melting Point/Range 275 °C / 527 °F
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula CaO2
Molecular Weight 72.08
SECTION 10. STABILITY AND REACTIVITY
Reactive Hazard Yes
Stability Oxidizer: Contact with combustible/organic material may cause fire.
Conditions to Avoid Incompatible products. Excess heat. Combustible material.
Incompatible Materials Strong reducing agents, Combustible material
Hazardous Decomposition Products None under normal use conditions
Hazardous Polymerization Hazardous polymerization does not occur.
Hazardous Reactions None under normal processing.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information
Component Information
Toxicologically Synergistic
Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure Respiratory system
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and
delayed
Product is a corrosive material. Use of gastric lavage or emesis is contraindicated.
Possible perforation of stomach or esophagus should be investigated: Ingestion causes
severe swelling, severe damage to the delicate tissue and danger of perforation
Endocrine Disruptor Information No information available
Other Adverse Effects The toxicological properties have not been fully investigated.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Persistence and Degradability No information available
Bioaccumulation/ Accumulation No information available.
Mobility No information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods
Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. Chemical waste generators must also consult local, regional, and
national hazardous waste regulations to ensure complete and accurate classification.
SECTION 14. TRANSPORT INFORMATION
DOT
UN-No UN1457
Proper Shipping Name CALCIUM PEROXIDE
Hazard Class 5.1
Packing Group II
TDG
UN-No UN1457
Proper Shipping Name CALCIUM PEROXIDE
Hazard Class 5.1
Packing Group II
IATA
UN-No UN1457
Proper Shipping Name CALCIUM PEROXIDE
Hazard Class 5.1
Packing Group II
IMDG/IMO
UN-No UN1457
Proper Shipping Name CALCIUM PEROXIDE
Hazard Class 5.1
Packing Group II
SECTION 15. REGULATORY INFORMATION
U.S. Federal Regulations
SARA 313 Not applicable
SARA 311/312 Hazard Categories See section 2 for more information
CWA (Clean Water Act) Not applicable
Clean Air Act Not applicable
OSHA - Occupational Safety and Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland
Security
This product does not contain any DHS chemicals.
Other International Regulations
Mexico - Grade No information available
