CAS No. 12036-43-0

Chemical Identifiers

Linear Formula ZnTiO3
Pubchem CID 166015
MDL Number MFCD00054107
EC No. 234-850-0
IUPAC Name zinc; oxygen(2-); titanium(4+)
Beilstein/Reaxys No. N/A
SMILES [Ti+4].[Zn+2].[O-2].[O-2].[O-2]
InchI Identifier InChI=1S/3O.Ti.Zn/q3*-2;+4;+2
InchI Key JRFBNCLFYLUNCE-UHFFFAOYSA-N

Health & Safety Information

Signal Word Warning
Hazard Statements H302
Hazard Codes Xn
Risk Codes 22
Safety Statements 36
RTECS Number N/A
Transport Information N/A
WGK Germany 3

View and Print SDS

SAFETY DATA SHEET

Date Accessed: 11/21/2024
Date Revised: 01/15/2022

SECTION 1. IDENTIFICATION

Product Identifiers: All applicable American Elements product codes for CAS #12036-43-0

Relevant identified uses of the substance: Scientific research and development

Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351

Emergency telephone number:
Domestic, North America +1 800-424-9300
International +1 703-527-3887


SECTION 2. HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Acute toxicity, Oral (Category 4), H302
2.2 GHS Label elements, including precautionary statements
Pictogram

Exclamation Mark - GHS07

Signal word Warning
Hazard statement(s)
H302 Harmful if swallowed.
Precautionary statement(s)
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you
feel unwell.
P330 Rinse mouth.
P501 Dispose of contents/ container to an approved waste disposal plant.
2.3 Hazards not otherwise classified (HNOC) or not covered by GHS - none


SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

3.1 Substances
Synonyms : Zinc titanium oxideFormula : O3TiZn
Molecular weight : 161.26 g/mol
CAS-No. : 12036-43-0
EC-No. : 234-850-0
Hazardous components
Component Classification Concentration
Titanium zinc trioxide
Acute Tox. 4; H302 <= 100 %


SECTION 4. FIRST AID MEASURES

4.1 Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
4.3 Indication of any immediate medical attention and special treatment needed
No data available


SECTION 5. FIREFIGHTING MEASURES

5.1 Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Titanium/titanium oxides, Zinc/zinc oxides
5.3 Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
5.4 Further information
No data available


SECTION 6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure adequate
ventilation. Avoid breathing dust.
For personal protection see section 8.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for
disposal.
6.4 Reference to other sections
For disposal see section 13.


SECTION 7. HANDLING AND STORAGE

7.1 Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.
For precautions see section 2.2.
7.2 Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Keep in a dry place.
7.3 Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated


SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
8.2 Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of
workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved
under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after
use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according to
the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level
protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Do not let product enter drains.


SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
a) Appearance Form: powder or solid
b) Odor No data available
c) Odor Threshold No data available
d) pH No data available
e) Melting point/freezing point No data available
f) Initial boiling point and boiling range No data available
g) Flash point N/A
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower flammability or explosive limits No data available
k) Vapor pressure No data available
l) Vapor density No data available
m) Relative density No data available
n) Water solubility No data available
o) Partition coefficient: noctanol/water No data available
p) Auto-ignition temperature No data available
q) Decomposition temperature No data available
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
9.2 Other safety information
No data available


SECTION 10. STABILITY AND REACTIVITY

10.1 Reactivity
No data available
10.2 Chemical stability
Stable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No data available
10.4 Conditions to avoid
No data available
10.5 Incompatible materials
Strong oxidizing agents
10.6 Hazardous decomposition products
Other decomposition products - No data available
In the event of fire: see section 5


SECTION 11. TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects
Acute toxicity
No data available
Inhalation: No data available
Dermal: No data available
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
No data available
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.


SECTION 12. ECOLOGICAL INFORMATION

12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
12.6 Other adverse effects
No data available


SECTION 13. DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a
chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.


SECTION 14. TRANSPORT INFORMATION

DOT (US)
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods


SECTION 15. REGULATORY INFORMATION

SARA 302 Components
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
The following components are subject to reporting levels established by SARA Title III, Section 313:
Titanium zinc trioxide
CAS-No.
12036-43-0
Revision Date
2007-07-01
SARA 311/312 Hazards
Acute Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
Titanium zinc trioxide
CAS-No.
12036-43-0
Revision Date
2007-07-01
New Jersey Right To Know Components
Titanium zinc trioxide
CAS-No.
12036-43-0
Revision Date
2007-07-01
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.


16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.


Reseach

  • Nanostructured zinc titanate wide band gap semiconductor as a photoelectrode material for quantum dot sensitized solar cells. Sahu A, Chaurashiya R, Hiremath K, Dixit A. Solar Energy. 2018 Mar 15;163:338-46.
  • High performance carbon-coated lithium zinc titanate as an anode material for lithium-ion batteries. Wang L, Chen B, Meng Z, Luo B, Wang X, Zhao Y. Electrochimica Acta. 2016 Jan 10;188:135-44.
  • Phase formation and electrical properties of zinc titanate ceramics. Naidu KC, Padma GT, Rao TS, Kumar NS, Raghuram N. Adv Mater. 2018;2:37-48.
  • Synthesis, characterization, and morphological control of ZnTiO3 nanoparticles through sol-gel processes and its photocatalyst application. Salavati-Niasari M, Soofivand F, Sobhani-Nasab A, Shakouri-Arani M, Faal AY, Bagheri S. Advanced Powder Technology. 2016 Sep 1;27(5):2066-75.
  • Carbothermal synthesis and photoluminescence characteristics of pure undoped ZnTiO3 nanocrystals. Raveendra RS, Prashanth PA, Hari Krishna R, Bhagya NP, Sathyanarayani S, Nagabhushana BM. J Adv Phys Sci. 2017;1:1-3.
  • Peroxide-based route for the synthesis of zinc titanate powder. N. V. Nikolenko, A. N. Kalashnykova, V. A. Solovov, A. O. Kostyniuk, F. Goutenoire. Arabian Journal of Chemistry, Volume 11, Issue 7, November 2018, Pages 1044-1052.
  • Solid state synthesis and structural characterization of zinc titanates. Sarra Ayed, Helmi Abdelkefi, Hamadi Khemakhem, Adel Matoussi. Journal of Alloys and Compounds, Volume 677, 25 August 2016, Pages 185-189.
  • Ultrasonic-assisted synthesis of Ce doped cubic–hexagonal ZnTiO3 with highly efficient sonocatalytic activity. Eskandarloo H, Badiei A, Behnajady MA, Tavakoli A, Ziarani GM. Ultrasonics Sonochemistry. 2016 Mar 1;29:258-69.
  • ZnTiO3/epoxy resin nanocomposites: Development, dielectric behaviour and functionality. Koufakis E, Mathioudakis GN, Patsidis AC, Psarras GC. Polymer Testing. 2019 Apr 17.
  • Influence of La-doping on phase transformation and photocatalytic properties of ZnTiO3 nanoparticles synthesized via modified sol-gel method. Surendar T, Kumar S, Shanker V. Phys Chem Chem Phys. 2014 Jan 14;16(2):728-35.