Catalytic Hydrodeoxygenation of High Carbon Furylmethanes to Renewable Jet-fuel Ranged Alkanes over a Rhenium-Modified Iridium Catalyst.

Title Catalytic Hydrodeoxygenation of High Carbon Furylmethanes to Renewable Jet-fuel Ranged Alkanes over a Rhenium-Modified Iridium Catalyst.
Authors S. Liu; S. Dutta; W. Zheng; N.S. Gould; Z. Cheng; B. Xu; B. Saha; D.G. Vlachos
Journal ChemSusChem
DOI 10.1002/cssc.201700863
Abstract

Renewable jet-fuel-range alkanes are synthesized by hydrodeoxygenation of lignocellulose-derived high-carbon furylmethanes over ReOx -modified Ir/SiO2 catalysts under mild reaction conditions. Ir-ReOx /SiO2 with a Re/Ir molar ratio of 2:1 exhibits the best performance, achieving a combined alkanes yield of 82-99?% from C12 -C15 furylmethanes. The catalyst can be regenerated in three consecutive cycles with only about 12?% loss in the combined alkanes yield. Mechanistically, the furan moieties of furylmethanes undergo simultaneous ring saturation and ring opening to form a mixture of complex oxygenates consisting of saturated furan rings, mono-keto groups, and mono-hydroxy groups. Then, these oxygenates undergo a cascade of hydrogenolysis reactions to alkanes. The high activity of Ir-ReOx /SiO2 arises from a synergy between Ir and ReOx , whereby the acidic sites of partially reduced ReOx activate the C-O bonds of the saturated furans and alcoholic groups while the Ir sites are responsible for hydrogenation with H2 .

Citation S. Liu; S. Dutta; W. Zheng; N.S. Gould; Z. Cheng; B. Xu; B. Saha; D.G. Vlachos.Catalytic Hydrodeoxygenation of High Carbon Furylmethanes to Renewable Jet-fuel Ranged Alkanes over a Rhenium-Modified Iridium Catalyst.. ChemSusChem. 2017. doi:10.1002/cssc.201700863

Related Elements

Iridium

See more Iridium products. Iridium (atomic symbol: Ir, atomic number: 77) is a Block D, Group 9, Period 6 element with an atomic weight of 192.217. The number of electrons in each of iridium's shells is [2, 8, 18, 32, 15, 2] and its electron configuration is [Xe] 4f14 5d7 6s2. Iridium Bohr ModelThe iridium atom has a radius of 136 pm and a Van der Waals radius of 202 pm. Iridium was discovered and first isolated by Smithson Tennant in 1803. In its elemental form, Iridium has a silvery white appearance. Iridium is a member of the platinum group of metals.Elemental Iridium It is the most corrosion resistant metal known and is the second-densest element (after osmium). It will not react with any acid and can only be attacked by certain molten salts, such as molten sodium chloride. Iridium is found as an uncombined element and in iridium-osmium alloys. Iridium's name is derived from the Greek goddess Iris, personification of the rainbow, on account of the striking and diverse colors of its salts.

Rhenium

See more Rhenium products. Rhenium (atomic symbol: Re, atomic number: 75) is a Block D, Group 7, Period 6 element with an atomic weight of 186.207. The number of electrons in each of rhenium's shells is 2, 8, 18, 32, 13, 2 and its electron configuration is [Xe] 4f14 5d5 6s2. Rhenium Bohr ModelThe rhenium atom has a radius of 137 pm and a Van der Waals radius of 217 pm. Rhenium was discovered and first isolated by Masataka Ogawa in 1908. In its elemental form, rhenium has a silvery-white appearance. Rhenium is the fourth densest element exceeded only by platinum, iridium, and osmium. Rhenium's high melting point is exceeded only by those of tungsten and carbon.Elemental Rhenium Rhenium is found in small amounts in gadolinite and molybdenite. It is usually extracted from the flue dusts of molybdenum smelters. The name Rhenium originates from the Latin word 'Rhenus' meaning "Rhine" after the place of discovery.