Cesium lead iodide solar cells controlled by annealing temperature.

Title Cesium lead iodide solar cells controlled by annealing temperature.
Authors Y.Geun Kim; T.Y. Kim; J.Hyeon Oh; K.Soon Choi; Y.J. Kim; S.Young Kim
Journal Phys Chem Chem Phys
DOI 10.1039/c6cp08177k
Abstract

An inorganic lead halide perovskite film, CsPbI3, used as an absorber in perovskite solar cells (PSCs) was optimized by controlling the annealing temperature and the layer thickness. The CsPbI3 layer was synthesized by one-step coating of CsI mixed with PbI2 and a HI additive in N,N-dimethylformamide. The annealing temperature of the CsPbI3 film was varied from 80 to 120 °C for different durations and the thickness was controlled by changing the spin-coating rpm. After annealing the CsPbI3 layer at 100 °C under dark conditions for 10 min, a black phase of CsPbI3 was formed and the band gap was 1.69 eV. Most of the yellow spots disappeared, the surface coverage was almost 100%, and the rms roughness was minimized to 3.03 nm after annealing at 100 °C. The power conversion efficiency (PCE) of the CsPbI3 based PSC annealed at 100 °C was 4.88%. This high PCE value is attributed to the low yellow phase ratio, high surface coverage, low rms roughness, lower charge transport resistance, and lower charge accumulation. The loss ratio of the PCE of the CH3NH3PbIxCl3-x and CsPbI3 based PSCs after keeping in air was 47 and 26%, respectively, indicating that the stability of the CsPbI3 based PSC is better than that of the CH3NH3PbIxCl3-x based PSC. From these results, it is evident that CsPbI3 is a potential candidate for solar cell applications.

Citation Y.Geun Kim; T.Y. Kim; J.Hyeon Oh; K.Soon Choi; Y.J. Kim; S.Young Kim.Cesium lead iodide solar cells controlled by annealing temperature.. Phys Chem Chem Phys. 2017;19(8):62576263. doi:10.1039/c6cp08177k

Related Elements

Cesium

See more Cesium products. Cesium (or Caesium) (atomic symbol: Ce, atomic number: 55) is a Block S, Group 1, Period 6 element with an atomic weight of 132.9054519. The number of electrons in each of Cesium's shells is 2, 8, 18, 18, 8, 1 and its electron configuration is [Xe]6s1. Cesium Bohr ModelThe cesium atom has a radius of 265 pm and a Van der Waals radius of 343 pm. Cesium is a member of the alkali group of metals. It is one of three metals that occur as a liquid at room temperature, the others being mercury and gallium. Elemental CesiumCesium's main commercial source is pollucite ore; however, it is also found in beryl, avogadrite, pezzottaite, and londonite. Cesium was discovered by Robert Bunsen and Gustav Kirchhoff in 1860 and first isolated by Carl Setterberg in 1882. In its elemental form, cesium has a silvery gold appearance. The word Cesium originates from the Latin word "caesius," meaning "sky blue," which refers to the vibrant blue lines in its spectrum.

Lead

Lead Bohr ModelSee more Lead products. Lead (atomic symbol: Pb, atomic number: 82) is a Block P, Group 14, Period 6 element with an atomic radius of 207.2. The number of electrons in each of Lead's shells is [2, 8, 18, 32, 18, 4] and its electron configuration is [Xe] 4f14 5d10 6s2 6p2. The lead atom has a radius of 175 pm and a Van der Waals radius of 202 pm. In its elemental form, lead has a metallic gray appearance. Lead occurs naturally as a mixture of four stable isotopes: 204Pb (1.48%), 206Pb (23.6%), 207Pb (22.6%), and 208Pb (52.3%). Elemental LeadLead is obtained mainly from galena (PbS) by a roasting process. Anglesite, cerussite, and minim are other common lead containing minerals. Lead does occur as a free element in nature, but it is rare. It is a dense, soft metal that is very resistant to corrosion and poorly conductive compared to other metals. Its density and low melting point make it useful in applications such as electrolysis and industrial materials.

Iodine

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

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