CO2 to methanol conversion using hydride terminated porous silicon nanoparticles.

Title CO2 to methanol conversion using hydride terminated porous silicon nanoparticles.
Authors M. Dasog; S. Kraus; R. Sinelnikov; J.G.C. Veinot; B. Rieger
Journal Chem Commun (Camb)
DOI 10.1039/c7cc00125h
Abstract

Porous silicon nanoparticles (Si-NPs) prepared via magnesiothermic reduction were used to convert carbon dioxide (CO2) into methanol. The hydride surface of the silicon nanoparticles acted as a CO2 reducing reagent without any catalyst at temperatures above 100 °C. The Si nanoparticles were reused up to four times without significant loss in methanol yields. The reduction process was monitored using in situ FT-IR and the materials were characterized using SEM, TEM, NMR, XPS, and powder XRD techniques. The influence of reaction temperature, pressure, and Si-NP concentration on CO2 reduction were also investigated. Finally, Si particles produced directly from sand were used to convert CO2 to methanol.

Citation M. Dasog; S. Kraus; R. Sinelnikov; J.G.C. Veinot; B. Rieger.CO2 to methanol conversion using hydride terminated porous silicon nanoparticles.. Chem Commun (Camb). 2017. doi:10.1039/c7cc00125h

Related Elements

Silicon

See more Silicon products. Silicon (atomic symbol: Si, atomic number: 14) is a Block P, Group 14, Period 3 element with an atomic weight of 28.085. Silicon Bohr MoleculeThe number of electrons in each of Silicon's shells is 2, 8, 4 and its electron configuration is [Ne] 3s2 3p2. The silicon atom has a radius of 111 pm and a Van der Waals radius of 210 pm. Silicon was discovered and first isolated by Jöns Jacob Berzelius in 1823. Silicon makes up 25.7% of the earth's crust, by weight, and is the second most abundant element, exceeded only by oxygen. The metalloid is rarely found in pure crystal form and is usually produced from the iron-silicon alloy ferrosilicon. Elemental SiliconSilica (or silicon dioxide), as sand, is a principal ingredient of glass, one of the most inexpensive of materials with excellent mechanical, optical, thermal, and electrical properties. Ultra high purity silicon can be doped with boron, gallium, phosphorus, or arsenic to produce silicon for use in transistors, solar cells, rectifiers, and other solid-state devices which are used extensively in the electronics industry.The name Silicon originates from the Latin word silex which means flint or hard stone.

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