Cobalt sulfide nanoparticles anchored in three-dimensional carbon nanosheet networks for lithium and sodium ion batteries with enhanced electrochemical performance.

Title Cobalt sulfide nanoparticles anchored in three-dimensional carbon nanosheet networks for lithium and sodium ion batteries with enhanced electrochemical performance.
Authors X. Zhang; H. Wang; G. Wang
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2016.12.071
Abstract

In order to improve the conductivity and electrochemical activity, Co9S8 nanoparticles anchored in three-dimensional carbon nanosheet networks (3D Co9S8@CNNs) are fabricated by a simple strategy with the assistance of NaCl. Combining the advantages of nanoscale and porous structure, 3D Co9S8@CNNs can retard the aggregation of Co9S8 nanoparticles, provide abundant electrochemical active sites, as well as accommodate the mechanical stress during the cycling of lithium ion batteries (LIBs) or sodium ion batteries (SIBs). Thus, when evaluated as an anode for LIBs, the as-prepared 3D Co9S8@CNNs electrode exhibits outstanding electrochemical performance with a high reversible capacity of 935mAhg(-1) after 200 cycles at 0.25Ag(-1). As for SIBs, it also delivers superior cycling stability with a capacity of 249mAhg(-1) after 50 cycles at 0.1Ag(-1). These results demonstrate that 3D Co9S8@CNNs composite has potential to be utilized as an anode material for LIBs/SIBs with enhanced electrochemical performance.

Citation X. Zhang; H. Wang; G. Wang.Cobalt sulfide nanoparticles anchored in three-dimensional carbon nanosheet networks for lithium and sodium ion batteries with enhanced electrochemical performance.. J Colloid Interface Sci. 2017;492:4150. doi:10.1016/j.jcis.2016.12.071

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Lithium

Lithium Bohr ModelSee more Lithium products. Lithium (atomic symbol: Li, atomic number: 3) is a Block S, Group 1, Period 2 element with an atomic weight of 6.94. The number of electrons in each of Lithium's shells is [2, 1] and its electron configuration is [He] 2s1. The lithium atom has a radius of 152 pm and a Van der Waals radius of 181 pm. Lithium was discovered by Johann Arvedson in 1817 and first isolated by William Thomas Brande in 1821. The origin of the name Lithium comes from the Greek wordlithose which means "stone." Lithium is a member of the alkali group of metals. It has the highest specific heat and electrochemical potential of any element on the period table and the lowest density of any elements that are solid at room temperature. Elemental LithiumCompared to other metals, it has one of the lowest boiling points. In its elemental form, lithium is soft enough to cut with a knife its silvery white appearance quickly darkens when exposed to air. Because of its high reactivity, elemental lithium does not occur in nature. Lithium is the key component of lithium-ion battery technology, which is becoming increasingly more prevalent in electronics.

Cobalt

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Sodium

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