Control of the optical properties of cadmium selenide nanoparticles using magadiite.

Title Control of the optical properties of cadmium selenide nanoparticles using magadiite.
Authors P. Poosimma; A. Ontam; S. Intachai; N. Khaorapapong; M. Ogawa
Journal Dalton Trans
DOI 10.1039/c7dt03297h
Abstract

The preparation of cadmium selenide nanoparticles in the interlayer space of magadiite, a layered sodium silicate, modified with the cetyltrimethylammonium cation was studied. The preparation was based on the formation of cadmium selenide by the reaction between the cetyltrimethylammonium modified magadiite and an aqueous mixture of cadmium sulfate and sodium selenosulfite at room temperature. The resulting hybrids were characterized by XRD, FT-IR, HRTEM, TG-DTA, as well as UV-visible and photoluminescence spectroscopy. The expansion of the interlayer spaces as well as TG-DTA results indicated the presence of the cetyltrimethylammonium cation and cadmium selenide in the hybrids. The HRTEM images showed the presence of cadmium selenide in the diameter range of 2-3 nm in the interlayer space of magadiite. The luminescence intensity of the cadmium selenide varied depending on the particle size, which was controlled by the loading amount of cadmium selenide precursor.

Citation P. Poosimma; A. Ontam; S. Intachai; N. Khaorapapong; M. Ogawa.Control of the optical properties of cadmium selenide nanoparticles using magadiite.. Dalton Trans. 2017. doi:10.1039/c7dt03297h

Related Elements

Cadmium

See more Cadmium products. Cadmium (atomic symbol: Cd, atomic number: 48) is a Block D, Group 12, Period 5 element with an atomic weight of 112.411. Cadmium Bohr ModelThe number of electrons in each of Cadmium's shells is 2, 8, 18, 18, 2 and its electron configuration is [Kr]4d10 5s2. The cadmium atom has a radius of 151 pm and a Van der Waals radius of 230 pm. Cadmium was discovered and first isolated by Karl Samuel Leberecht Hermann and Friedrich Stromeyer in 1817. In its elemental form, cadmium has a silvery bluish gray metallic appearance. Cadmium makes up about 0.1 ppm of the earth's crust. Elemental CadmiumNo significant deposits of cadmium containing ores are known, however, it is sometimes found in its metallic form. It is a common impurity in zinc ores and is isolated during the production of zinc. Cadmium is a key component in battery production and particular pigments and coatings due to its distinct yellow color. Cadmium oxide is used in phosphors for television picture tubes. The name Cadmium originates from the Latin word 'cadmia' and the Greek word 'kadmeia'.

Selenium

Selenium Bohr ModelSee more Selenium products. Selenium (atomic symbol: Se, atomic number: 34) is a Block P, Group 16, Period 4 element with an atomic radius of 78.96. The number of electrons in each of Selenium's shells is 2, 8, 18, 6 and its electron configuration is [Ar] 3d10 4s2 4p4. The selenium atom has a radius of 120 pm and a Van der Waals radius of 190 pm. Selenium is a non-metal with several allotropes: a black, vitreous form with an irregular crystal structure three red-colored forms with monoclinic crystal structures and a gray form with a hexagonal crystal structure, the most stable and dense form of the element. Elemental SeleniumOne of the most common uses for selenium is in glass production the red tint that it lends to glass neutralizes green or yellow tints from impurities in the glass materials. Selenium was discovered and first isolated by Jöns Jakob Berzelius and Johann Gottlieb Gahn in 1817. The origin of the name Selenium comes from the Greek word "Selênê," meaning moon.

Related Forms & Applications