SECTION 2. HAZARDS IDENTIFICATION

GHS-US classification
Flammable liquids Category 4 H227 Combustible liquid
Acute toxicity (oral) Category 4 H302 Harmful if swallowed
Skin corrosion/irritation Category 2 H315 Causes skin irritation
Serious eye damage/eye irritation Category 2A H319 Causes serious eye irritation

Signal word (GHS US) : Warning
Hazard statements (GHS US) :
H227 - Combustible liquid
H302 - Harmful if swallowed
H315 - Causes skin irritation
H319 - Causes serious eye irritation
Precautionary statements (GHS US) :
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P210 - Keep away from heat, open flames, sparks. - No smoking.
P264 - Wash hands thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P330 - Rinse mouth.
P301+P312 - If swallowed: Call a doctor if you feel unwell
P302+P352 - If on skin: Wash with plenty of water
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P337+P313 - If eye irritation persists: Get medical advice/attention.
P321 - Specific treatment (see first aid instructions on this label)
P362+P364 - Take off contaminated clothing and wash it before reuse.
P370+P378 - In case of fire: Use water spray, foam, carbon dioxide, dry chemical to extinguish.
P403+P235 - Keep in a cool place
P501 - Dispose of contents/container to licensed waste disposal facility.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Copper(I)/(II) hexafluoro-2,4-pentanedionatevinyltrimethylsilane complex
CAS #: 139566-53-3
GHS-US classification:
Flam. Liq. 4, H227
Acute Tox. 4 (Oral), H302
Skin Irrit. 2, H315
Eye Irrit. 2A, H319

SECTION 4. FIRST AID MEASURES

Description of First Aid Measures
General Advice:
Remove contaminated clothing and shoes. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). If possible show this sheet; if not available show packaging or label. IF exposed or concerned: Get medical advice/attention.
Inhalation:
Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice.
Skin Contact:
Wash with plenty of soap and water. Get medical advice/attention.
Eye Contact:
Immediately flush eyes thoroughly with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical advice/attention.
Most important symptoms and effects (acute and delayed)
Inhalation:
May cause irritation to the respiratory tract.
Skin Contact:
Causes skin irritation. Decomposition products are potentially sensitizing.
Eye Contact:
Causes serious eye irritation.
Ingestion:
Harmful if swallowed. Swallowing a small quantity of this material will result in serious health
hazard.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media:
Water spray. Foam. Carbon dioxide. Dry chemical.
Unsuitable extinguishing media:
Water.
Fire hazard:
Combustible liquid. Irritating fumes and organic acid vapors may develop when material is exposed to elevated temperatures or open flame.
Firefighting instructions:
Use water spray to cool exposed surfaces. Exercise caution when fighting any chemical fire.
Protection during firefighting:
Do not enter fire area without proper protective equipment, including respiratory protection. Wear pressure demand self-contained breathing apparatus with full facepiece and full protective clothing. Avoid all eye and skin contact and do not breathe vapor and mist.

SECTION 6. ACCIDENTAL RELEASE MEASURES

General measures:
Remove ignition sources. Use special care to avoid static electric charges.
Protective equipment :
Wear protective equipment as described in Section 8.
Emergency procedures :
Evacuate unnecessary personnel.
Protective equipment:
Equip cleanup crew with proper protection. Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection".
Environmental Precautions:
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
For containment:
Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for cleaning up:
Clean up any spills as soon as possible, using an absorbent material to collect it. Sweep or shovel spills into appropriate container for disposal. Use only non-sparking tools.

SECTION 7. HANDLING AND STORAGE

Additional hazards when processed:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Precautions for safe handling:
Avoid all eye and skin contact and do not breathe vapor and mist. Use only non-sparking tools.
Ground/bond container and receiving equipment.
Hygiene measures:
Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash contaminated clothing before reuse.
Storage conditions:
Keep container tightly closed. Keep in a cool place.
Incompatible materials:
Water.
Storage area:
Store in a well-ventilated place. Store away from heat.

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Appropriate engineering controls:
Provide local exhaust or general room ventilation.
Personal protective equipment:
Avoid all unnecessary exposure. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.
Hand protection:
Neoprene or nitrile rubber gloves
Eye protection:
Chemical goggles. Contact lenses should not be worn
Skin and body protection:
Wear suitable protective clothing
Respiratory protection:
Where exposure through inhalation may occur from use, respiratory protection equipment is recommended. NIOSH-certified dust and mist (orange cartridge) respirator.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state : Liquid
Appearance : Liquid.
Molecular mass : 370.84 g/mol
Color : Green.
Odor : No data available
Odor threshold : No data available
Refractive index : No data available
pH : No data available
Relative evaporation rate (butyl acetate=1) : No data available
Melting point : -5 °C
Freezing point : No data available
Boiling point : 50 °C @ 50 mm Hg
Flash point : 72 °C
Auto-ignition temperature : 340 °C
Decomposition temperature : No data available
Flammability (solid, gas) : Combustible liquid
Vapor pressure : No data available
Relative vapor density at 20 °C : > 1
Relative density : 1.49
Solubility : Insoluble in water. Reacts with water.
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
Explosion limits : ≥ 0.3 vol % (lower)

SECTION 10. STABILITY AND REACTIVITY

Chemical stability:
Stable below 25°C. Slowly decomposes at elevated temperature.
Possibility of hazardous reactions:
Material decomposes slowly in contact with air by reaction with water.
Conditions to avoid:
Heat. Open flame. Sparks.
Incompatible materials:
Water
Hazardous decomposition products
Copper oxide fumes. Fluorinated organic vapors. Organic acids.

SECTION 11. TOXICOLOGICAL INFORMATION

ATE US (oral) 622.222 mg/kg body weight
LD50 oral rat 560 mg/kg
ATE US (oral) 560 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
Serious eye damage/irritation : Causes serious eye irritation.
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity – single exposure : Not classified
Specific target organ toxicity – repeated exposure: Not classified
Aspiration hazard : Not classified
Symptoms/effects after inhalation : May cause irritation to the respiratory tract.
Symptoms/effects after skin contact : Causes skin irritation. Decomposition products are potentially sensitizing.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : Harmful if swallowed. Swallowing a small quantity of this material will result in serious health hazard.
Reason for classification : Expert judgment

SECTION 12. ECOLOGICAL INFORMATION

Toxicity:
No additional information available
Persistence and degradability:
No additional information available
Bioaccumulative potential:
No additional information available
Mobility in soil:
No additional information available
Other adverse effects
Other adverse effects : This substance may be hazardous to the environment.
Effect on the ozone layer : No additional information available

SECTION 13. DISPOSAL CONSIDERATIONS

Sewage disposal recommendations:
Do not dispose of waste into sewer.
Product/Packaging disposal recommendations:
Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to licensed waste disposal facility.
Ecology - waste materials:
Avoid release to the environment.

SECTION 14. TRANSPORT INFORMATION

DOT NA no.:
NA1993
Transport document description : NA1993 Combustible liquid, n.o.s. (COPPER(I)/(II) HEXAFLUORO-2,4-PENTANEDIONATEVINYLTRIMETHYLSILANE COMPLEX), 3, III
Proper Shipping Name (DOT) : Combustible liquid, n.o.s.
(COPPER(I)/(II) HEXAFLUORO-2,4-PENTANEDIONATE-VINYLTRIMETHYLSILANE
COMPLEX)
Class (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120
Packing group (DOT) : III - Minor Danger
DOT Packaging Non Bulk (49 CFR 173.xxx) : 203
DOT Packaging Bulk (49 CFR 173.xxx) : 241
DOT Packaging Exceptions (49 CFR 173.xxx) : 150
DOT Symbols : D - Proper shipping name for domestic use only, or to and from Canada,G - Identifies PSN
requiring a technical name
DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 60 L
DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75)

SECTION 15. REGULATORY INFORMATION

TSCA Exemption/Exclusion CAUTION:
This material is supplied for research and development purposes subject to the R&D exemption under TSCA, 40 CFR 720.36, and must meet the requirements of the exemption, including supervision by a "technically qualified individual" as defined by 40 CFR 720.3(ee). The use
of this material for "commercial purposes" as defined by 40 CFR 720.3(r) is not permitted in the United States.