SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
GHS02 GHS07
Signal word
Warning
Hazard-determining components of labeling:
Naphthenic acids, copper salts
Hazard statements
H226 Flammable liquid and vapor.
H302 Harmful if swallowed.
Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403+P233
Store in a well-ventilated place. Keep container tightly closed.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
Health = 1
Fire = 2
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Mixtures
Description:
Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
1338-02-9 Naphthenic acids, copper salts
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
If inhaled:
Supply fresh air; consult doctor in case of complaints.
In case of skin contact:
Immediately rinse with water.
In case of eye contact:
Rinse opened eye for several minutes under running water. Consult a physician.
If swallowed:
Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed
No data available
Indication of any immediate medical attention and special treatment needed
No data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents:
Water with full jet
Special hazards arising from the substance or mixture
No data available
Advice for firefighters
Protective equipment:
No special measures required.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Keep unprotected persons away.
Environmental precautions:
Do not allow product to enter drains, sewage systems, or other water courses.
Prevent seepage into sewage system, workpits and cellars.
Inform respective authorities in case of seepage into water courses, or sewage systems.
Methods and materials for containment and cleanup:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
Handling:
Precautions for safe handling
No special precautions are necessary if used correctly.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities:
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Not required.
Further information about storage conditions:
Keep receptacle tightly sealed.
Specific end use(s)
No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
None.
Additional information:
The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Breathing equipment:
Not required.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
Tightly sealed goggles
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Appearance:
Form: Liquid
Color: Dark green
Odor: Characteristic
Odor threshold: No data available.
pH: No data available.
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
Flash point: 40 °C (104 °F)
Flammability (solid, gas): No data available.
Ignition temperature: 229 °C (444 °F)
Decomposition temperature: No data available.
Autoignition: Product is not selfigniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapor
mixtures are possible.
Explosion limits:
Lower: No data available.
Upper: No data available.
Vapor pressure: No data available.
Density: No data available.
Relative density
No data available.
Vapor density
No data available.
Evaporation rate
No data available.
Solubility in Water (H2O): Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): No data available.
Viscosity:
Dynamic: No data available.
Kinematic: No data available.
Solvent content:
Organic solvents:
0.0 %
VOC content:
0.0 g/l / 0.00 lb/gl
Other information
No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity
No data available
Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known.
Conditions to avoid
No data available
Incompatible materials:
No data available
Hazardous decomposition products:
No dangerous decomposition products known.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin:
No irritant effect.
on the eye:
No irritating effect.
Sensitization:
No sensitizing effects known.
Additional toxicological information:
Harmful
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No data available
Persistence and degradability
No data available
Behavior in environmental systems:
Bioaccumulative potential
No data available
Mobility in soil
No data available
Additional ecological information:
Not known to be hazardous to water.
Results of PBT and vPvB assessment
PBT:
N/A
vPvB:
N/A
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to enter drains, sewage systems, or other water courses system.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA
UN1993
UN proper shipping name
DOT
Flammable liquids, n.o.s.
IMDG
FLAMMABLE LIQUID, N.O.S.
IATA
Flammable liquid, n.o.s.
Transport hazard class(es)
DOT
Class
3 Flammable liquids
Label
3
IMDG, IATA
Class
3 Flammable liquids
Label
3
Packing group
DOT, IMDG, IATA
III
Environmental hazards:
Product contains environmentally hazardous substances:
Naphthenic acids, copper salts
Marine pollutant: No
Special precautions for user
Warning: Flammable liquids
Danger code (Kemler): 30
EMS Number: F-E,S-E
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N/A
Transport/Additional information:
DOT
Quantity limitations
On passenger aircraft/rail: 60 L
On cargo aircraft only: 220 L
IMDG
Limited quantities (LQ)
5L
Excepted quantities (EQ)
Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
UN "Model Regulation":
UN 1993 FLAMMABLE LIQUIDS, N.O.S., 3, III
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
All ingredients are listed.
TSCA (Toxic Substances Control Act):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
EPA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.