Different dominant transitions in holmium and ytterbium codoped oxyfluoride glass and glass ceramics originating from varying phonon energy environments.

Title Different dominant transitions in holmium and ytterbium codoped oxyfluoride glass and glass ceramics originating from varying phonon energy environments.
Authors Q. Liu; Y. Tian; C. Wang; F. Huang; X. Jing; J. Zhang; X. Zhang; S. Xu
Journal Phys Chem Chem Phys
DOI 10.1039/c7cp06638d
Abstract

Transparent oxyfluoride glass and glass ceramics doped with 0.5% Ho3+ and 1.0% Yb3+ ions have been prepared. X-ray diffraction and transmission electron microscopy demonstrated the formation of NaYF4 nanocrystals during the heat treatment process. Raman spectra indicated the variation of glass structure brought about by the formation of NaYF4 nanocrystals. XRD curves and Judd-Ofelt intensity parameters confirmed the incorporation of Ho3+ into NaYF4 nanocrystals. Significantly enhanced visible upconversion and 2.85 ?m emissions were achieved in glass ceramic under 980 nm laser diode pumping. A broadband spectrum with a full-width at half-maximum close to 132 nm was obtained in the glass ceramic. Besides, the calculated peak emission cross section was 0.6 × 10-20 cm2, suggesting that the glass ceramic is a promising gain material that can be applied to broadband amplifiers in the mid-infrared region. Furthermore, energy transfer mechanisms in glass and glass ceramics were proposed based on visible to mid-infrared emission spectra. It was found that the change in the photon energy environment around rare earth ions induced different dominant transitions in glass and glass ceramic. Finally, the influence of phonon energy on the transition processes was further quantitatively investigated, which may provide useful guidance for obtaining highly efficient 2.85 ?m emission of holmium.

Citation Q. Liu; Y. Tian; C. Wang; F. Huang; X. Jing; J. Zhang; X. Zhang; S. Xu.Different dominant transitions in holmium and ytterbium codoped oxyfluoride glass and glass ceramics originating from varying phonon energy environments.. Phys Chem Chem Phys. 2017;19(44):2983329839. doi:10.1039/c7cp06638d

Related Elements

Holmium

See more Holmium products. Holmium (atomic symbol: Ho, atomic number: 67) is a Block F, Group 3, Period 6 element with an atomic radius of 164.93032. Holmium Bohr ModelThe number of electrons in each of Holmium's shells is [2, 8, 18, 29, 8, 2] and its electron configuration is [Xe] 4f11 6s2. Elemental Holmium PictureThe holmium atom has a radius of 176 pm and its Covalent radius is 192±7 pm. Holmium was first discovered by Marc Delafontaine in 1878. In its elemental form, holmium has a silvery white appearance. It is relatively soft and malleable. It is stable in dry air at room temperature but rapidly oxidizes at elevated temperatures and in moist air. Holmium has unusual magnetic properties. Its name is derived from the Latin word Holmia meaning Stockholm.

Ytterbium

See more Ytterbium products. Ytterbium (atomic symbol: Yb, atomic number: 70) is a Block F, Group 3, Period 6 element with an atomic weight of 173.054. Ytterbium Bohr ModelThe number of electrons in each of Ytterbium's shells is [2, 8, 18, 32, 8, 2] and its electron configuration is [Xe]4f14 6s2. The Ytterbium atom has a radius of 176 pm and a Van der Waals radius of 242 pm. Ytterbium was discovered by Jean Charles Galissard de Marignac in 1878 and first isolated by Georges Urbain in 1907.Elemental Ytterbium In its elemental form, ytterbium has a silvery-white color. Ytterbium is found in monazite sand as well as the ores euxenite and xenotime. Ytterbium is named after Ytterby, a village in Sweden. Ytterbium can be used as a source for gamma rays, for the doping of stainless steel, or other active metals. Its electrical resistivity rises under stress, making it very useful for stress gauges that measure the deformation of the ground in the even of an earthquake.

Fluorine

Fluorine is a Block P, Group 17, Period 2 element. Its electron configuration is [He]2s22p5. The fluorine atom has a covalent radius of 64 pm and its Van der Waals radius is 135 pm. In its elemental form, CAS 7782-41-4, fluorine gas has a pale yellow appearance. Fluorine was discovered by André-Marie Ampère in 1810. It was first isolated by Henri Moissan in 1886.

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