Efficient CO2 Insertion and Reduction Catalyzed by a Terminal Zinc Hydride Complex.

Title Efficient CO2 Insertion and Reduction Catalyzed by a Terminal Zinc Hydride Complex.
Authors M. Tüchler; L. Gärtner; S. Fischer; A.Daniel Boese; F. Belaj; N.C. Mösch-Zanetti
Journal Angew Chem Int Ed Engl
DOI 10.1002/anie.201801800
Abstract

The terminal zinc hydride complex [Tntm]ZnH (2) (Tntm = tris(6-tert-butyl-3-thiopyridazinyl)methanide) was found to be an efficient hydrosilylation catalyst of CO2 for the first time at room temperature without the need of Lewis acidic additives. The inherent electrophilicity of the system leads to selective formation of the monosilylated product (MeO)3SiO2CH (at room temperature with a TOF of 22.2 h-1 and at 45°C with a TOF of 66.7 h-1). In absence of silanes the intermediate formate complex [Tntm]Zn(O2CH) (3) is quantitatively formed within 5 min. All complexes are fully characterized via 1H and 13C NMR spectroscopy and single crystal X-ray diffraction analyses. Density functional theory (DFT) calculations reveal a high positive charge on zinc and the increased preference of the ligand to adopt a ?3-coordination mode.

Citation M. Tüchler; L. Gärtner; S. Fischer; A.Daniel Boese; F. Belaj; N.C. Mösch-Zanetti.Efficient CO2 Insertion and Reduction Catalyzed by a Terminal Zinc Hydride Complex.. Angew Chem Int Ed Engl. 2018. doi:10.1002/anie.201801800

Related Elements

Zinc

See more Zinc products. Zinc (atomic symbol: Zn, atomic number: 30) is a Block D, Group 12, Period 4 element with an atomic weight of 65.38. The number of electrons in each of zinc's shells is 2, 8, 18, 2, and its electron configuration is [Ar] 3d10 4s2. Zinc Bohr ModelThe zinc atom has a radius of 134 pm and a Van der Waals radius of 210 pm. Zinc was discovered by Indian metallurgists prior to 1000 BC and first recognized as a unique element by Rasaratna Samuccaya in 800. Zinc was first isolated by Andreas Marggraf in 1746. In its elemental form, zinc has a silver-gray appearance. It is brittle at ordinary temperatures but malleable at 100 °C to 150 °C.Elemental Zinc It is a fair conductor of electricity, and burns in air at high red producing white clouds of the oxide. Zinc is mined from sulfidic ore deposits. It is the 24th most abundant element in the earth's crust and the fourth most common metal in use (after iron, aluminum, and copper). The name zinc originates from the German word "zin," meaning tin.

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