Electrochemical sensor for detection of hydrogen peroxide modified with prussian blue electrodeposition on nitrogen, phosphorus and sulfur co-doped porous carbons-chitosan.

Title Electrochemical sensor for detection of hydrogen peroxide modified with prussian blue electrodeposition on nitrogen, phosphorus and sulfur co-doped porous carbons-chitosan.
Authors X. Zhai; Y. Li; J. Li; C. Yue; X. Lei
Journal Mater Sci Eng C Mater Biol Appl
DOI 10.1016/j.msec.2016.11.106
Abstract

Nitrogen, phosphorus and sulfur co-doped porous carbons (N, P, S@PC) were well dispersed in the chitosan (CS) acid solution, in particular via covalently interaction, which could avoid the aggregation of N, P, S@PC in most solvents. Moreover, CS could also avoid N, P, S@PC leakage from the modified electrode. A novel electrochemical sensor was then developed through prussian blue (PB) was electrodeposited on the glass carbon (GC) electrode modified with N, P, S@PC-CS composite. Results with scanning electron microscopy image, illustrate that PB/N, P, S@PC-CS composite distributes very uniformly on the substrate surface, which is hoped to be very attractive for determination of hydrogen peroxide (H2O2). Due to synergistic effect between PB and N, P, S@PC, the PB/N, P, S@PC-CS/GC electrode exhibited excellent conductive and electrocatalytical activity towards H2O2. Under a low applied potential of -0.174V, H2O2 could be linearly detected from 0.4?M to 2.0mM with a low detection limit of 0.2?M (S/N=3) and fast response time of 2s. These results indicate that the electrochemical sensor prepared with PB/N, P, S@PC- CS composite has promising applications for real analysis applications of H2O2.

Citation X. Zhai; Y. Li; J. Li; C. Yue; X. Lei.Electrochemical sensor for detection of hydrogen peroxide modified with prussian blue electrodeposition on nitrogen, phosphorus and sulfur co-doped porous carbons-chitosan.. Mater Sci Eng C Mater Biol Appl. 2017;77:12421246. doi:10.1016/j.msec.2016.11.106

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