Electrochemical synthesis of nitrogen-doped carbon quantum dots decorated copper oxide for the sensitive and selective detection of non-steroidal anti-inflammatory drug in berries.

Title Electrochemical synthesis of nitrogen-doped carbon quantum dots decorated copper oxide for the sensitive and selective detection of non-steroidal anti-inflammatory drug in berries.
Authors G. Muthusankar; R. Sasikumar; S.M. Chen; G. Gopu; N. Sengottuvelan; S.P. Rwei
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2018.03.095
Abstract

We report a sensitive non-steroidal anti-inflammatory drug aspirin (ASA) sensor studies using the nitrogen-doped carbon quantum dots (N-CQD) decorated copper oxide (CuO). A simplistic approach of electrochemical deposition method has been used to prepare the N-CQD incorporated with copper oxide (N-CQD/CuO) and the resulting composite has characterized by analytical techniques. Modified glassy carbon electrode of N-CQD/CuO/GCE is developed and is used for the sensor studies of aspirin. The modified N-CQD/CuO/GCE has exhibited a higher current (I) response to the oxidation process when compared to N-CQD/GCE, CuO/GCE and bare GCE. Furthermore, it has shown a good linear range of 1-907?µM with a limit of detection (LOD) ?0.002?µM and sensitivity ?21.87?µA?µM?cm. The developed sensor has displayed outstanding repeatability, stability and accumulation time along with better electro-catalytic response in berries for real-life application.

Citation G. Muthusankar; R. Sasikumar; S.M. Chen; G. Gopu; N. Sengottuvelan; S.P. Rwei.Electrochemical synthesis of nitrogen-doped carbon quantum dots decorated copper oxide for the sensitive and selective detection of non-steroidal anti-inflammatory drug in berries.. J Colloid Interface Sci. 2018;523:191200. doi:10.1016/j.jcis.2018.03.095

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