Enhanced photocatalytic hydrogen generation from barium tantalate composites.

Title Enhanced photocatalytic hydrogen generation from barium tantalate composites.
Authors R. Marschall; J. Soldat; W. Busser; M. Wark
Journal Photochem Photobiol Sci
DOI 10.1039/c2pp25200g
Abstract

(111)-layered Ba5Ta4O15 photocatalysts were synthesised by a solid state reaction route and a citrate synthesis route, and their structural and electronic properties were investigated. After citrate route preparation, the presence of a second phase, namely Ba3Ta5O15, was determined by X-ray powder diffraction and absorption spectroscopy. The existence of this phase had a profound effect on the photocatalytic activity of this Ba5Ta4O15/Ba3Ta5O15 composite in comparison to the pure Ba5Ta4O15 materials. The photocatalytic performance of the barium tantalates was evaluated by investigating the capability in ?OH radical formation and hydrogen generation. Strongly increased hydrogen evolution rates for the Ba5Ta4O15/Ba3Ta5O15 composite, up to 160% higher than for the pure Ba5Ta4O15, were determined, and only very small amounts of Rh co-catalyst, deposited on the photocatalysts by stepwise reductive photo-deposition, were needed to achieve these results.

Citation R. Marschall; J. Soldat; W. Busser; M. Wark.Enhanced photocatalytic hydrogen generation from barium tantalate composites.. Photochem Photobiol Sci. 2013;12(4):6717. doi:10.1039/c2pp25200g

Related Elements

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Barium

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