Facile access to unsymmetrically substituted tellurium-boron based heterocycles.

Title Facile access to unsymmetrically substituted tellurium-boron based heterocycles.
Authors F.An Tsao; D.W. Stephan
Journal Chem Commun (Camb)
DOI 10.1039/c7cc03648e
Abstract

Reactions of Te-B heterocycles Te((Ph)C[double bond, length as m-dash]C(C6F5))2B(C6F5) 1 with alcohols is shown to afford species of the form Te((Ph)C[double bond, length as m-dash]C(C6F5))2BOR. The subsequent reaction with either 4-Br-C6H4CCH or 3-(C4H3S)CCH proceeds with the liberation of C6F5CCPh to give unsymmetrically substituted Te-B based heterocycles of the form Te((Ph)C[double bond, length as m-dash]C(C6F5))(HC[double bond, length as m-dash]CR)BOCH2Ph.

Citation F.An Tsao; D.W. Stephan.Facile access to unsymmetrically substituted tellurium-boron based heterocycles.. Chem Commun (Camb). 2017. doi:10.1039/c7cc03648e

Related Elements

Boron

See more Boron products. Boron Bohr ModelBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808 and was first isolated by Humphry Davy later that year. Boron is classified as a metalloid is not found naturally on earth. Elemental BoronAlong with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax.

Tellurium

See more Tellurium products. Tellurium (atomic symbol: Te, atomic number: 52) is a Block P, Group 16, Period 5 element with an atomic radius of 127.60. Tellurium Bohr ModelThe number of electrons in each of tellurium's shells is 2, 8, 18, 18, 6 and its electron configuration is [Kr] 4d10 5s2 5p4. Tellurium was discovered by Franz Muller von Reichenstein in 1782 and first isolated by Martin Heinrich Klaproth in 1798. In its elemental form, tellurium has a silvery lustrous gray appearance. The tellurium atom has a radius of 140 pm and a Van der Waals radius of 206 pm. Elemental TelluriumTellurium is most commonly sourced from the anode sludges produced as a byproduct of copper refining. The name Tellurium originates from the Greek word Tellus, meaning Earth.

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