Facile visual colorimetric sensor based on iron carbide nanoparticles encapsulated in porous nitrogen-rich graphene.

Title Facile visual colorimetric sensor based on iron carbide nanoparticles encapsulated in porous nitrogen-rich graphene.
Authors S. Wu; H. Huang; X. Feng; C. Du; W. Song
Journal Talanta
DOI 10.1016/j.talanta.2017.02.003
Abstract

Herein, via one-step pyrolysis of glucose, dicyandiamide (DCDA) and Fe containing metal-organic framework (Fe-MOF), small Fe3C nanoparticles were in-situ decorated in 3D porous network of N-rich graphene (NGr). The Fe-MOF served as size regulating precursor, layered g-C3N4 (derived from pyrolysis of DCDA) acted as not only a template to guide the growth of small Fe3C nanoparticles, but also the carbon source for 3D porous NGr network. The intrinsic peroxidase-like catalytic activity of Fe3C/NGr was unpredictably discovered, by taking the oxidation reaction of 3,3',5,5'-tetramethylbenzidine (TMB) with H2O2 as a protocol. Fast and distinguished color change, improved stability in exposure to extreme H2O2 concentration and high temperature were obtained. The Michaelis-Menten kinetics was investigated. The detection of glucose was accomplished over a wide concentration range of 2.0~500.0?M with a detection limit lower than most of other similar systems. The reliability of the present sensor was further evaluated by practical monitoring glucose in diluted serum samples. Low cost and simple preparation, fast and distinguished color change, high tolerance to extreme H2O2 concentration and high temperature, endow Fe3C/NGr as one of the promising materials for fast visual colorimetry.

Citation S. Wu; H. Huang; X. Feng; C. Du; W. Song.Facile visual colorimetric sensor based on iron carbide nanoparticles encapsulated in porous nitrogen-rich graphene.. Talanta. 2017;167:385391. doi:10.1016/j.talanta.2017.02.003

Related Elements

Iron

See more Iron products. Iron (atomic symbol: Fe, atomic number: 26) is a Block D, Group 8, Period 4 element with an atomic weight of 55.845. The number of electrons in each of Iron's shells is 2, 8, 14, 2 and its electron configuration is [Ar] 3d6 4s2. Iron Bohr ModelThe iron atom has a radius of 126 pm and a Van der Waals radius of 194 pm. Iron was discovered by humans before 5000 BC. In its elemental form, iron has a lustrous grayish metallic appearance. Iron is the fourth most common element in the Earth's crust and the most common element by mass forming the earth as a whole. Iron is rarely found as a free element, since it tends to oxidize easily; it is usually found in minerals such as magnetite, hematite, goethite, limonite, or siderite.Elemental Iron Though pure iron is typically soft, the addition of carbon creates the alloy known as steel, which is significantly stronger.

Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

Carbon

See more Carbon products. Carbon (atomic symbol: C, atomic number: 6) is a Block P, Group 14, Period 2 element. Carbon Bohr ModelThe number of electrons in each of Carbon's shells is 2, 4 and its electron configuration is [He]2s2 2p2. In its elemental form, carbon can take various physical forms (known as allotropes) based on the type of bonds between carbon atoms; the most well known allotropes are diamond, graphite, amorphous carbon, glassy carbon, and nanostructured forms such as carbon nanotubes, fullerenes, and nanofibers . Carbon is at the same time one of the softest (as graphite) and hardest (as diamond) materials found in nature. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element (by mass) in the universe after hydrogen, helium, and oxygen. Carbon was discovered by the Egyptians and Sumerians circa 3750 BC. It was first recognized as an element by Antoine Lavoisier in 1789.

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