Fast and scalable synthesis of uniform zirconium-, hafnium-based metal-organic framework nanocrystals.

Title Fast and scalable synthesis of uniform zirconium-, hafnium-based metal-organic framework nanocrystals.
Authors T. He; X. Xu; B. Ni; H. Wang; Y. Long; W. Hu; X. Wang
Journal Nanoscale
DOI 10.1039/c7nr06274e
Abstract

Metal-organic frameworks based on zirconium or hafnium possess tantalizing commercial prospects due to their high stability but require a long reaction time to form crystals. The fast synthesis of uniform Zr-, Hf-MOF nanocrystals at scale is of key importance in the potential commercial application of MOFs. In this work, we have developed a versatile strategy through controlling the hydrolysis and nucleation of metal salts in the presence of acetic acid and water; up to 24 grams of UiO-66-NH2 nanocrystals with a uniform octahedron could be synthesized within 15 minutes using a one step method. The current synthetic strategy could be extended to other Zr-, Hf-MOF nanocrystals [UiO-66-Fast, UiO-66-(OH)2-Fast, UiO-66-2,6-NDC-Fast, UiO-67-Fast, BUT-12-Fast, PCN-222-Ni-Fast, PCN-222-Co-Fast, Hf-UiO-66-Fast, Hf-UiO-66-NH2-Fast, Hf-UiO-66-(OH)2-Fast, Hf-UiO-66-2,6-NDC-Fast and Hf-BUT-12-Fast]. Significantly, when noble metal nanoparticles (NPs) are introduced into MOF precursors, NPs encapsulated in MOFs with excellent dispersion have also been obtained and show outstanding performance in catalysis. This facile procedure is expected to pave the way to expand the commercial applications of MOFs.

Citation T. He; X. Xu; B. Ni; H. Wang; Y. Long; W. Hu; X. Wang.Fast and scalable synthesis of uniform zirconium-, hafnium-based metal-organic framework nanocrystals.. Nanoscale. 2017;9(48):1920919215. doi:10.1039/c7nr06274e

Related Elements

Hafnium

See more Hafnium products. Hafnium (atomic symbol: Hf, atomic number: 72) is a Block D, Group 4, Period 6 element with an atomic weight of 178.49. Hafnium Bohr ModelThe number of electrons in each of Hafnium's shells is 2, 8, 18, 32, 10, 2 and its electron configuration is [Xe] 4f14 5d2 6s2. The hafnium atom has a radius of 159 pm and a Van der Waals radius of 212 pm. Hafnium was predicted by Dmitri Mendeleev in 1869 but it was not until 1922 that it was first isolated Dirk Coster and George de Hevesy. In its elemental form, hafnium has a lustrous silvery-gray appearance. Elemental HafniumHafnium does not exist as a free element in nature. It is found in zirconium compounds such as zircon. Hafnium is often a component of superalloys and circuits used in semiconductor device fabrication. Its name is derived from the Latin word Hafnia, meaning Copenhagen, where it was discovered.

Zirconium

See more Zirconium products. Zirconium (atomic symbol: Zr, atomic number: 40) is a Block D, Group 4, Period 5 element with an atomic weight of 91.224. Zirconium Bohr ModelThe number of electrons in each of Zirconium's shells is 2, 8, 18, 10, 2 and its electron configuration is [Kr]4d2 5s2. The zirconium atom has a radius of 160 pm and a Van der Waals radius of 186 pm. Zirconium was discovered by Martin Heinrich Klaproth in 1789 and first isolated by Jöns Jakob Berzelius in 1824. In its elemental form, zirconium has a silvery white appearance that is similar to titanium. Zirconium's principal mineral is zircon (zirconium silicate). Elemental ZirconiumZirconium is commercially produced as a byproduct of titanium and tin mining and has many applications as a opacifier and a refractory material. It is not found in nature as a free element. The name of zirconium comes from the mineral zircon, the most important source of zirconium, and from the Persian wordzargun, meaning gold-like.

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