GeTe(2)O(6), a germanium tellurate(IV) with an open framework.

Title GeTe(2)O(6), a germanium tellurate(IV) with an open framework.
Authors N.Jennene Boukharrata; P. Thomas; J.P. Laval
Journal Acta Crystallogr C
DOI 10.1107/S0108270109010488
Abstract

The structure of an already evidenced but still uncharacterized GeTe(2)O(6) phase consists of isolated GeO(6) octahedra connected via isolated TeO(3) units. The germanium cations occupy a site with 1 symmetry. The Te and O atoms are in general positions of the P2(1)/n space group. This structure corresponds to a new type of tetravalent tellurate and is different from other AB(2)X(6) structures in which the B cation presents a stereochemically active electronic lone pair. It derives from the pseudo-hexagonal MI(2)O(6) (M = Mg, Mn, Co and Fe) type by a strong monoclinic distortion caused by the much smaller size of Ge(4+) compared with the divalent M cations.

Citation N.Jennene Boukharrata; P. Thomas; J.P. Laval.GeTe(2)O(6), a germanium tellurate(IV) with an open framework.. Acta Crystallogr C. 2009;65(Pt 5):i236. doi:10.1107/S0108270109010488

Related Elements

Tellurium

See more Tellurium products. Tellurium (atomic symbol: Te, atomic number: 52) is a Block P, Group 16, Period 5 element with an atomic radius of 127.60. Tellurium Bohr ModelThe number of electrons in each of tellurium's shells is 2, 8, 18, 18, 6 and its electron configuration is [Kr] 4d10 5s2 5p4. Tellurium was discovered by Franz Muller von Reichenstein in 1782 and first isolated by Martin Heinrich Klaproth in 1798. In its elemental form, tellurium has a silvery lustrous gray appearance. The tellurium atom has a radius of 140 pm and a Van der Waals radius of 206 pm. Elemental TelluriumTellurium is most commonly sourced from the anode sludges produced as a byproduct of copper refining. The name Tellurium originates from the Greek word Tellus, meaning Earth.

Germanium

See more Germanium products. Germanium (atomic symbol: Ge, atomic number: 32) is a Block P, Group 14, Period 4 element with an atomic weight of 72.63. Germanium Bohr ModelThe number of electrons in each of germanium's shells is 2, 8, 18, 4 and its electron configuration is [Ar] 3d10 4s2 4p2. The germanium atom has a radius of 122.5 pm and a Van der Waals radius of 211 pm. Germanium was first discovered by Clemens Winkler in 1886. In its elemental form, germanium is a brittle grayish white semi-metallic element. Germanium is too reactive to be found naturally on Earth in its native state. High Purity (99.999%) Germanium (Ge) MetalIt is commercially obtained from zinc ores and certain coals. It is also found in argyrodite and germanite. It is used extensively as a semiconductor in transitors, solar cells, and optical materials. Other applications include acting an alloying agent, as a phosphor in fluorescent lamps, and as a catalyst. The name Germanium originates from the Latin word "Germania" meaning "Germany."

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