Graphene oxide-assisted facile synthesis of platinum-tellurium nanocubes with enhanced catalytic activity for formic acid electro-oxidation.

Title Graphene oxide-assisted facile synthesis of platinum-tellurium nanocubes with enhanced catalytic activity for formic acid electro-oxidation.
Authors Y. Wang; J. Chen; F. Zhou; J. Zhang; X. Wei; R. Luo; G. Wang; R. Wang
Journal Nanotechnology
DOI 10.1088/1361-6528/aa7987
Abstract

In order to obtain a loaded Pt-based catalyst with enhanced high activity and stability towards formic acid electro-oxidation (FAO), PtTe nanoparticles loaded on graphene oxide (GO) were fabricated by a facile and scalable method. XRD and HRTEM results show that the morphology of PtTe particles could be affected by the additive amount of GO and Te. It is observed that the supported PtTe particles are cubic. The XPS results show the change in the Pt electronic structure after the incorporation of Te, which impedes the chemisorption of the CO intermediate and promotes the dehydrogenation pathway of FAO. By electrochemical analysis, the performance towards FAO is greatly enhanced. The mass activity of PtTe/GO-67 is at 0.45 V (versus SCE), which is 11.5 times as high as that of Pt/C The incorporation of Te atoms and the content of GO are two major parameters for tuning the crystal structure and morphology and enhancing catalytic activity.

Citation Y. Wang; J. Chen; F. Zhou; J. Zhang; X. Wei; R. Luo; G. Wang; R. Wang.Graphene oxide-assisted facile synthesis of platinum-tellurium nanocubes with enhanced catalytic activity for formic acid electro-oxidation.. Nanotechnology. 2017;28(33):335701. doi:10.1088/1361-6528/aa7987

Related Elements

Platinum

See more Platinum products. Platinum (atomic symbol: Pt, atomic number: 78) is a Block D, Group 10, Period 6 element with an atomic weight of 195.084. The number of electrons in each of platinum's shells is [2, 8, 18, 32, 17, 1] and its electron configuration is [Xe] 4f14 5d9 6s1. The platinum atom has a radius of 139 pm and a Van der Waals radius of 175 pm. Platinum Bohr ModelElemental PlatinumPlatinum was discovered and first isolated by Antonio de Ulloa in 1735. It is one of the rarest elements in the earth's crust, occurring at a concentration of only 0.005 ppm. Platinum is found uncombined as a free element and alloyed with iridium as platiniridium. In its elemental form, platinum has a grayish white appearance. It is highly resistant to corrosion: the metal does not oxidize in air at any temperature. It is generally non-reactive, even at high temperatures. The origin of the name "platinum" comes from the Spanish word platina, meaning silver.

Tellurium

See more Tellurium products. Tellurium (atomic symbol: Te, atomic number: 52) is a Block P, Group 16, Period 5 element with an atomic radius of 127.60. Tellurium Bohr ModelThe number of electrons in each of tellurium's shells is 2, 8, 18, 18, 6 and its electron configuration is [Kr] 4d10 5s2 5p4. Tellurium was discovered by Franz Muller von Reichenstein in 1782 and first isolated by Martin Heinrich Klaproth in 1798. In its elemental form, tellurium has a silvery lustrous gray appearance. The tellurium atom has a radius of 140 pm and a Van der Waals radius of 206 pm. Elemental TelluriumTellurium is most commonly sourced from the anode sludges produced as a byproduct of copper refining. The name Tellurium originates from the Greek word Tellus, meaning Earth.

Carbon

See more Carbon products. Carbon (atomic symbol: C, atomic number: 6) is a Block P, Group 14, Period 2 element. Carbon Bohr ModelThe number of electrons in each of Carbon's shells is 2, 4 and its electron configuration is [He]2s2 2p2. In its elemental form, carbon can take various physical forms (known as allotropes) based on the type of bonds between carbon atoms; the most well known allotropes are diamond, graphite, amorphous carbon, glassy carbon, and nanostructured forms such as carbon nanotubes, fullerenes, and nanofibers . Carbon is at the same time one of the softest (as graphite) and hardest (as diamond) materials found in nature. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element (by mass) in the universe after hydrogen, helium, and oxygen. Carbon was discovered by the Egyptians and Sumerians circa 3750 BC. It was first recognized as an element by Antoine Lavoisier in 1789.

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