Growth and structure of ultrathin praseodymium oxide layers on ruthenium(0001).

Title Growth and structure of ultrathin praseodymium oxide layers on ruthenium(0001).
Authors J. Höcker; J.O. Krisponeit; J. Cambeis; A. Zakharov; Y. Niu; G. Wei; L.Colombi Ciacchi; J. Falta; A. Schaefer; J.Ingo Flege
Journal Phys Chem Chem Phys
DOI 10.1039/c6cp06853g
Abstract

The growth, morphology, structure, and stoichiometry of ultrathin praseodymium oxide layers on Ru(0001) were studied using low-energy electron microscopy and diffraction, photoemission electron microscopy, atomic force microscopy, and X-ray photoelectron spectroscopy. At a growth temperature of 760 °C, the oxide is shown to form hexagonally close-packed (A-type) Pr2O3(0001) islands that are up to 3 nm high. Depending on the local substrate step density, the islands either adopt a triangular shape on sufficiently large terraces or acquire a trapezoidal shape with the long base aligned along the substrate steps.

Citation J. Höcker; J.O. Krisponeit; J. Cambeis; A. Zakharov; Y. Niu; G. Wei; L.Colombi Ciacchi; J. Falta; A. Schaefer; J.Ingo Flege.Growth and structure of ultrathin praseodymium oxide layers on ruthenium(0001).. Phys Chem Chem Phys. 2017;19(5):34803485. doi:10.1039/c6cp06853g

Related Elements

Praseodymium

See more Praseodymium products. Praseodymium (atomic symbol: Pr, atomic number: 59) is a Block F, Group 3, Period 6 element with an atomic weight of 140.90765. Praseodymium Bohr Model The number of electrons in each of praseodymium's shells is 2, 8, 18, 21, 8, 2 and its electron configuration is [Xe]4f3 6s2. The praseodymium atom has a radius of 182 pm and a Van der Waals radius of 239 pm. Praseodymium resembles the typical trivalent rare earths, however, it will exhibit a +4 state when stabilized in a zirconia host. Elemental PraseodymiumUnlike other rare-earth metals, which show antiferromagnetic and / or ferromagnetic ordering at low temperatures, praseodymium is paramagnetic at any temperature above 1 K. Praseodymium is found in the minerals monazite and bastnasite. Praseodymium was discovered by Carl Auer von Welsbach in 1885. The origin of the element name comes from the Greek words prasios didymos, meaning green twin.

Ruthenium

See more Ruthenium products. Ruthenium (atomic symbol: Ru, atomic number: 44) is a Block D, Group 8, Period 5 element with an atomic weight of 101.07. Ruthenium Bohr ModelThe number of electrons in each of ruthenium's shells is [2, 8, 18, 15, 1] and its electron configuration is [Kr] 4d7 5s1. The ruthenium atom has a radius of 134 pm and a Van der Waals radius of 207 pm. Ruthenium was discovered by Jędrzej Śniadecki in 1807. It was first recognized as a distinct element by Karl Ernst Claus in 1844. Elemental RutheniumIn its elemental form, ruthenium has a silvery white metallic appearance. Ruthenium is a rare transition metal belonging to the platinum group of metals. It is found in pentlandite, pyroxenite, and platinum group metal ores. The name Ruthenium originates from the Latin word "Ruthenia," meaning Russia.

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