Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature.

Title Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature.
Authors O. Nazarenko; M.R. Kotyrba; S. Yakunin; M. Aebli; G. Rainò; B.M. Benin; M. Wörle; M.V. Kovalenko
Journal J Am Chem Soc
DOI 10.1021/jacs.8b00194
Abstract

Two-dimensional hybrid organic-inorganic lead halides perovskite-type compounds have attracted immense scientific interest due to their remarkable optoelectronic properties and tailorable crystal structures. In this work, we present a new layered hybrid lead halide, namely [CH(NH)][C(NH)]PbI, wherein puckered lead-iodide layers are separated by two small and stable organic cations: formamidinium, CH(NH), and guanidinium, C(NH). This perovskite is thermally stable up to 255 °C, exhibits room-temperature photoluminescence in the red region with a quantum yield of 3.5%, and is photoconductive. This study highlights a vast structural diversity that exists in the compositional space typically used in perovskite photovoltaics.

Citation O. Nazarenko; M.R. Kotyrba; S. Yakunin; M. Aebli; G. Rainò; B.M. Benin; M. Wörle; M.V. Kovalenko.Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature.. J Am Chem Soc. 2018. doi:10.1021/jacs.8b00194

Related Elements

Lead

Lead Bohr ModelSee more Lead products. Lead (atomic symbol: Pb, atomic number: 82) is a Block P, Group 14, Period 6 element with an atomic radius of 207.2. The number of electrons in each of Lead's shells is [2, 8, 18, 32, 18, 4] and its electron configuration is [Xe] 4f14 5d10 6s2 6p2. The lead atom has a radius of 175 pm and a Van der Waals radius of 202 pm. In its elemental form, lead has a metallic gray appearance. Lead occurs naturally as a mixture of four stable isotopes: 204Pb (1.48%), 206Pb (23.6%), 207Pb (22.6%), and 208Pb (52.3%). Elemental LeadLead is obtained mainly from galena (PbS) by a roasting process. Anglesite, cerussite, and minim are other common lead containing minerals. Lead does occur as a free element in nature, but it is rare. It is a dense, soft metal that is very resistant to corrosion and poorly conductive compared to other metals. Its density and low melting point make it useful in applications such as electrolysis and industrial materials.

Iodine

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

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