Heterobimetallic scandium-group 10 metal complexes with LM ? Sc (LM = Ni, Pd, Pt) dative bonds.

Title Heterobimetallic scandium-group 10 metal complexes with LM ? Sc (LM = Ni, Pd, Pt) dative bonds.
Authors P. Cui; C. Xiong; J. Du; Z. Huang; S. Xie; H. Wang; S. Zhou; H. Fang; S. Wang
Journal Dalton Trans
DOI 10.1039/c9dt04369a
Abstract

Heterobimetallic scandium complexes with whole group 10 metals were synthesized. All Sc-LM complexes were characterized by NMR spectroscopy, X-ray diffraction analysis and computational studies, which revealed notable LM ? Sc (LM = Ni, Pd, Pt) dative bonding interactions in these heterobimetallic systems. Versatile coordination modes toward apical donors were observed in these heterobimetallic Sc-LM complexes, among which the Sc-Ni complexes 2 and 3 were reversibly bound to N and the Sc-Pt complex 5 was coordinated to an additional PPh ligand, while in the Sc-Pd complex 4 no apical donor was ligated.

Citation P. Cui; C. Xiong; J. Du; Z. Huang; S. Xie; H. Wang; S. Zhou; H. Fang; S. Wang.Heterobimetallic scandium-group 10 metal complexes with LM ? Sc (LM = Ni, Pd, Pt) dative bonds.. Dalton Trans. 2020;49(1):124130. doi:10.1039/c9dt04369a

Related Elements

Scandium

See more Scandium products. Scandium (atomic symbol: Sc, atomic number: 21) is a Block D, Group 3, Period 4 element with an atomic weight of 44.955912. The number of electrons in each of Scandium's shells is [2, 8, 9, 2] and its electron configuration is [Ar] 3d1 4s2. Scandium Bohr Model The scandium atom has a radius of 162 pm and a Van der Waals radius of 216 pm.Scandium was predicted by Dmitri Mendeleev in 1871 and actually discovered and isolated by Lars Nilson in 1879. One of the transition metals, scandium has a silvery-white appearance in its elemental form which oxidizes to yellow or pinkish upon contact with air. Elemental ScandiumIt is occasionally included in the classification of the rare earth elements. Scandium is found in concentrated amounts in the minerals euxenite, gadolinite and thortveitite however, due to the difficulties in the preparation of metallic scandium, global trade of the pure metal is very limited. The origin of the name scandium comes from the Latin word 'scandia' meaning Scandinavia.

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