High-Pressure Synthesis and Characterization of the Ammonium Yttrium Borate (NH4)YB8O14.

Title High-Pressure Synthesis and Characterization of the Ammonium Yttrium Borate (NH4)YB8O14.
Authors M.K. Schmitt; M. Podewitz; K.R. Liedl; H. Huppertz
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b02402
Abstract

The first high-pressure yttrium borate (NH4)YB8O14 was synthesized at 12.8 GPa/1300 °C using a Walker-type multianvil module. The compound crystallizes in the orthorhombic space group Pnma (no. 62) with the lattice parameters a = 17.6375(9), b = 10.7160(5), and c = 4.2191(2) Å. (NH4)YB8O14 constitutes a novel structure type but exhibits similarities to the crystal structure of ?-BaB4O7. X-ray single-crystal and powder diffraction, EDX, vibrational spectroscopy as well as quantum chemical calculations were used to characterize (NH4)YB8O14.

Citation M.K. Schmitt; M. Podewitz; K.R. Liedl; H. Huppertz.High-Pressure Synthesis and Characterization of the Ammonium Yttrium Borate (NH4)YB8O14.. Inorg Chem. 2017;56(22):1429114299. doi:10.1021/acs.inorgchem.7b02402

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