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Hoveyda-Grubbs Catalyst, 1st Generation

CAS #:

203714-71-0

Linear Formula:

C₂₈H₄₅Cl₂OPRu

MDL Number:

MFCD03453042

EC No.:

N/A

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PRODUCT	Product Code	ORDER	SAFETY DATA	TECHNICAL DATA
Hoveyda-Grubbs Catalyst 1st Generation, Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)	RU-OMX-01-P	Pricing >	SDS >	Data Sheet >

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Hoveyda-Grubbs Catalyst, 1st Generation Properties (Theoretical)

Compound Formula	C₂₈H₄₅Cl₂OPRu
Molecular Weight	600.61
Appearance	Faint to dark brown powder
Melting Point	195-197 °C
Boiling Point	N/A
Density	N/A
Solubility in H2O	N/A
Storage Temperature	2-8 °C
Exact Mass	600.163 g/mol
Monoisotopic Mass	600.163 g/mol

Hoveyda-Grubbs Catalyst, 1st Generation Health & Safety Information

Signal Word	Warning
Hazard Statements	H228
Hazard Codes	F
Precautionary Statements	P210
RTECS Number	N/A
Transport Information	UN1325 4.1/PG II
WGK Germany	3
GHS Pictograms	GHS02 Flame
MSDS / SDS	Request MSDS / SDS

About Hoveyda-Grubbs Catalyst, 1st Generation

First Generation Hoveyda-Grubbs Catalyst, or Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II), is an organometallic ruthenium complex used in Ring-Closing Metathesis (RCM) to form macrocycles. American Elements supplies organometallic catalysts in most volumes including bulk quantities and also can produce materials to customer specifications. Most materials can be produced in high and ultra high purity forms (99%, 99.9%, 99.99%, 99.999%, and higher) and to many standard grades when applicable including Mil Spec (military grade), ACS, Reagent and Technical Grades, Pharmaceutical Grades, Optical, Semiconductor, and Electronics Grades. Please request a quote above for more information on pricing and lead time.

Hoveyda-Grubbs Catalyst, 1st Generation Synonyms

HG-I, Dichloro(2-isopropoxyphenylmethylene) (tricyclohexylphosphine)ruthenium(II), Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II), Grubbs Catalyst C601, First Generation Hoveyda-Grubbs Catalyst, Ruthenium, dichloro(2-isopropoxyphenylmethylene)tricyclohexylphosphine

Chemical Identifiers

Linear Formula	C₂₈H₄₅Cl₂OPRu
MDL Number	MFCD03453042
EC No.	N/A
Pubchem CID	10941020
IUPAC Name	dichloro-[(2-propan-2-yloxyphenyl)methylidene]ruthenium; tricyclohexylphosphane
SMILES	CC(C)OC1=CC=CC=C1C=[Ru](Cl)Cl.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
InchI Identifier	InChI=1S/C18H33P.C10H12O.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)11-10-7-5-4-6-9(10)3;;;/h16-18H,1-15H2;3-8H,1-2H3;2*1H;/q;;;;+2/p-2
InchI Key	KMKCJXPECJFQPQ-UHFFFAOYSA-L

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Packaging Specifications

Typical bulk packaging includes palletized plastic 5 gallon/25 kg. pails, fiber and steel drums to 1 ton super sacks in full container (FCL) or truck load (T/L) quantities. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. Shipping documentation includes a Certificate of Analysis and Safety Data Sheet (SDS). Solutions are packaged in polypropylene, plastic or glass jars up to palletized 440 gallon liquid totes, and 36,000 lb. tanker trucks.

Related Elements

Chlorine

17 Cl 35.453000000 Chlorine

Chlorine is a Block P, Group 17, Period 3 element. Its electron configuration is [Ne]3s²3p⁵. The chlorine atom has a covalent radius of 102±4 pm and its Van der Waals radius is 175 pm. Chlorine Model In its elemental form, chlorine is a yellow-green gas. Chlorine is the second lightest halogen after fluorine. It has the third highest electronegativity and the highest electron affinity of all elements, making it a strong oxidizing agent. It is rarely found by itself in nature. Chlorine was discovered and first isolated by Carl Wilhelm Scheele in 1774. It was first recognized as an element by Humphry Davy in 1808.

Phosphorus

15 P 30.973762000 Phosphorus

See more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s² 3p³. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.

Ruthenium

44 Ru 101.070000000 Ruthenium

See more Ruthenium products. Ruthenium (atomic symbol: Ru, atomic number: 44) is a Block D, Group 8, Period 5 element with an atomic weight of 101.07. Ruthenium Bohr Model The number of electrons in each of ruthenium's shells is [2, 8, 18, 15, 1] and its electron configuration is [Kr] 4d⁷ 5s¹. The ruthenium atom has a radius of 134 pm and a Van der Waals radius of 207 pm. Ruthenium was discovered by Jędrzej Śniadecki in 1807. It was first recognized as a distinct element by Karl Ernst Claus in 1844. Elemental Ruthenium In its elemental form, ruthenium has a silvery white metallic appearance. Ruthenium is a rare transition metal belonging to the platinum group of metals. It is found in pentlandite, pyroxenite, and platinum group metal ores. The name Ruthenium originates from the Latin word "Ruthenia," meaning Russia.