Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate.

Title Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate.
Authors J. Jia; P. Ma; P. Zhang; D. Zhang; C. Zhang; J. Niu; J. Wang
Journal Dalton Trans
DOI 10.1039/c8dt00138c
Abstract A monomeric trinickel(ii)-substituted phosphotungstate [H9P2W15O62Ni3]9- ion is stabilized by grafting three {Re(CO)3} organometallic groups on the surface for the first time. Magnetic measurements manifest that the resulting complex, Na(NH4)5[P2W15O56Ni3(H2O)3(?3-OH)3(Re(CO)3)3]·18H2O (1), displays overall ferromagnetic interactions with the presence of ZFS for Ni2+ at low temperature.
Citation J. Jia; P. Ma; P. Zhang; D. Zhang; C. Zhang; J. Niu; J. Wang.Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate.. Dalton Trans. 2018;47(18):62886292. doi:10.1039/c8dt00138c

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