In-Plane Black Phosphorus/Dicobalt Phosphide Heterostructure for Efficient Electrocatalysis.

Title In-Plane Black Phosphorus/Dicobalt Phosphide Heterostructure for Efficient Electrocatalysis.
Authors J. Wang; D. Liu; H. Huang; N. Yang; B. Yu; M. Wen; X. Wang; P.K. Chu; X.F. Yu
Journal Angew Chem Int Ed Engl
DOI 10.1002/anie.201710859
Abstract

Heterostructures composed of two-dimensional black phosphorus (2D BP) with unique physical/chemical properties are of great interest. Herein, we report a simple solvothermal method to synthesize in-plane BP/Co2P heterostructures for electrocatalysis. By using the reactive edge defects of the BP nanosheets as the initial sites, Co2P nanocrystals are selectively grown on the BP edges to form the in-plane BP/Co2P heterostructures. Owing to disposition on the original defects of BP, Co2P improves the conductivity and offers more active electrocatalytic sites, so that the BP/Co2P nanosheets exhibit better and more stable electrocatalytic activities in the hydrogen evolution and oxygen evolution reactions. Our work not only extends the application of BP to electrochemistry, but also provides a new idea to improve the performance of BP by utilization of defects. Furthermore, this strategy can be extended to produce other BP heterostructures to expand the corresponding applications.

Citation J. Wang; D. Liu; H. Huang; N. Yang; B. Yu; M. Wen; X. Wang; P.K. Chu; X.F. Yu.In-Plane Black Phosphorus/Dicobalt Phosphide Heterostructure for Efficient Electrocatalysis.. Angew Chem Int Ed Engl. 2017. doi:10.1002/anie.201710859

Related Elements

Cobalt

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar]3d7 4s2. The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit.

Phosphorus

Phosphorus Bohr ModelSee more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.

Related Forms & Applications