Isolation of Blackberry-Shaped Nanoparticles of a Giant {Mo72Fe30} Cluster and Their Transformation to a Crystalline Nanoferric Molybdate.

Title Isolation of Blackberry-Shaped Nanoparticles of a Giant {Mo72Fe30} Cluster and Their Transformation to a Crystalline Nanoferric Molybdate.
Authors R. Mekala; S. Supriya; S.K. Das
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.6b02292
Abstract

When an aqueous solution of sodium molybdate is added to an aqueous solution of ferric chloride, acidified with acetic acid, a giant {Mo72Fe30} cluster is instantaneously formed as the amorphous substance Na2[Mo72Fe30O252(CH3COO)4(OH)16(H2O)108]·180 H2O (1). Compound 1 consists of aggregated nanovesicles of {Mo72Fe30} clusters, as confirmed by field-emission scanning electron microscopy and transmission electron microscopy images of 1. An aqueous suspension of 1 upon moderate heating results in the formation of crystalline nanoferric molybdate, which gives insight into understanding the formation of a yellow coating mineral, ferrimolybdite, frequently found on the ores of molybdenum.

Citation R. Mekala; S. Supriya; S.K. Das.Isolation of Blackberry-Shaped Nanoparticles of a Giant {Mo72Fe30} Cluster and Their Transformation to a Crystalline Nanoferric Molybdate.. Inorg Chem. 2016;55(24):1250412507. doi:10.1021/acs.inorgchem.6b02292

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