K8Ce2I18O53: a novel potassium cerium(iv) iodate with enhanced visible light driven photocatalytic activity resulting from polar zero dimensional [Ce(IO3)8](4-) units.

Title K8Ce2I18O53: a novel potassium cerium(iv) iodate with enhanced visible light driven photocatalytic activity resulting from polar zero dimensional [Ce(IO3)8](4-) units.
Authors R. Wu; X. Jiang; M. Xia; L. Liu; X. Wang; Z. Lin; C. Chen
Journal Dalton Trans
DOI 10.1039/c7dt00185a
Abstract

Hydrothermally grown iodate, K8Ce2I18O53, featuring polar 0D [Ce(IO3)8](4-) units, has shown the highest visible light driven (VLD) photocatalytic activity in metal iodates reported before. The enhanced VLD photocatalytic property results from a synergistic effect between the narrow band gap and polar 0D [Ce(IO3)8](4-) units, as confirmed using first principles calculations.

Citation R. Wu; X. Jiang; M. Xia; L. Liu; X. Wang; Z. Lin; C. Chen.K8Ce2I18O53: a novel potassium cerium(iv) iodate with enhanced visible light driven photocatalytic activity resulting from polar zero dimensional [Ce(IO3)8](4-) units.. Dalton Trans. 2017;46(13):41704173. doi:10.1039/c7dt00185a

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