SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture
GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)
Substances and mixtures, which in contact with water, emit flammable gases (Category 1), H260
For the full text of the H - Statements mentioned in this Section, see Section 16.
GHS Label elements, including precautionary statements
Pictogram

Signal word: Danger
Hazard statement(s)
H260
In contact with water releases flammable gases which may ignite spontaneously.
Precautionary statement(s)
P223
Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231 + P232
Handle under inert gas. Protect from moisture.
P280
Wear protective gloves/ protective clothing/ eye protection/ face protection.
P335 + P334
Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages.
P370 + P378
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
P402 + P404
Store in a dry place. Store in a closed container.
P501
Dispose of contents/ container to an approved waste disposal plan
Hazards not otherwise classified (HNOC) or not covered by GHS
Reacts violently with water.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances
Formula: La
Molecular Weight: 138.91 g/mol
CAS-No.: 7439-91-0
EC-No.: 231-099-0
No ingredients are hazardous according to OSHA criteria.
No components need to be disclosed according to the applicable regulations.
For the full text of the H - Statements mentioned in this Section, see Section 1

SECTION 4. FIRST AID MEASURES

Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed: no data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media
Suitable extinguishing media
Dry powder
Special hazards arising from the substance or mixture
Lanthanum oxides
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information: no data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.
For personal protection see section 8
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains
Methods and materials for containment and cleaning up
Sweep up and shovel. Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (see section 13). Do not flush with water.
Keep in suitable, closed containers for disposa
Reference to other sections
For disposal see section 13

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.Keep away from sources of ignition - No smoking.
For precautions see section 2.2
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place.
Never allow product to get in contact with water during storage.
Air and moisture sensitive.
Keep in a dry place.
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Personal protective equipment
Eye/face protection
Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
Body Protection
Flame retardant protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
Prevent further leakage or spillage if safe to do so. Do not let product enter drain

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties
Appearance
Form: powder
Colour: gray
Odor: no data available
Odor Threshold: no data available
pH: no data available
Melting point/freezing point
Melting point/range: 920 °C (1,688 °F)-lit.
Initial boiling point and boiling range: 3,464 °C (6,267 °F)-lit.
Flash point: no data available
Evaporation rate: no data available
Flammability (solid, gas): no data available
Upper/lower flammability or explosive limits: no data available
Vapor pressure: no data available
Vapor density: no data available
Relative density: 6.19 g/mL at 25 °C (77 °F)
Water solubility: no data available
Partition coefficient: n-octanol/water: no data available
Auto-ignition temperature: no data available
Decomposition temperature: no data available
Viscosity: no data available
Explosive properties: no data available
Oxidizing properties: no data available

SECTION 10. STABILITY AND REACTIVITY

Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
Reacts violently with water.
Conditions to avoid
Exposure to moisture.
Incompatible materials
Strong acids, Strong oxidizing agents, Halogens, Phosphorus, Sulphur compounds
Hazardous decomposition products
Other decomposition products-no data available
In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects
Acute toxicity
no data available
Inhalation: no data available
Dermal:
no data available
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitisation
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC:
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH:
No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP:
No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
OSHA:
No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: Not available
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated

SECTION 12. ECOLOGICAL INFORMATION

Toxicity
no data available
Persistence and degradability:
no data available
Bioaccumulative potential:
no data available
Mobility in soil:
no data available
Results of PBT and vPvB assessment:
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects
no data available

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Product
Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable.
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contact a licensed professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product

SECTION 14. TRANSPORT INFORMATION

DOT (US)
UN number: 3208
Class: 4.3
Packing group: I
Proper shipping name: Metallic substance, water-reactive, n.o.s. (Lanthanum)
Reportable Quantity (RQ):
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 3208
Class: 4.3
Packing group: I
EMS-No: F-G, S-N
Proper shipping name:
METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S. (Lanthanum)
Marine pollutant: No
IATA
UN number:3208
Class: 4.3
Packing group: I
Proper shipping name: Metallic substance, water-reactive, n.o.s. (Lanthanum)
IATA Passenger: Not permitted for transport

SECTION 15. REGULATORY INFORMATION

SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 311/312 Hazards
Reactivity Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm