SECTION 2. HAZARDS IDENTIFICATION

Classification:
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Flammable liquids Category 3
Acute oral toxicity Category 4
Acute Inhalation Toxicity - Vapors Category 4
Germ Cell Mutagenicity Category 1B
Carcinogenicity Category 1B
Reproductive Toxicity Category 1A
Specific target organ toxicity - (repeated exposure) Category 1
Aspiration Toxicity Category 1
Signal Word: Danger
Hazard Statements:
Flammable liquid and vapor
Harmful if swallowed
May be fatal if swallowed and enters airways
Harmful if inhaled
May cause genetic defects
May cause cancer
May damage the unborn child. Suspected of damaging fertility
Causes damage to organs through prolonged or repeated exposure

Precautionary Statements
Prevention:
Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Keep container tightly closed
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Use only non-sparking tools
Take precautionary measures against static discharge
Response:
IF exposed or concerned: Get medical attention/advice
Inhalation:
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Skin:
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
Ingestion:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
Do NOT induce vomiting
Rinse mouth
Fire:
In case of fire: Use CO2, dry chemical, or foam for extinction
Storage:
Store locked up
Store in a well-ventilated place. Keep cool
Disposal:
Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC):
Very toxic to aquatic life with long lasting effects
Repeated exposure may cause skin dryness or cracking

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component / CAS-No:
Lead naphthenate / 61790-14-5
Stoddard solvent / 8052-41-3

SECTION 4. FIRST AID MEASURES

General Advice:
If symptoms persist, call a physician.
Eye Contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact:
Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician.
Inhalation:
Move to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms occur. Risk of serious damage to the lungs.
Ingestion:
Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting. Call a physician or Poison Control Center immediately. If vomiting occurs naturally, have victim lean forward.
Most important symptoms and effects:
Breathing difficulties. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting
Notes to Physician:
Treat symptomatically

SECTION 5. FIREFIGHTING MEASURES

Suitable Extinguishing Media:
Cool closed containers exposed to fire with water spray.
Unsuitable Extinguishing Media:
No information available
Flash Point 40 °C / 104 °F
Method - No information available
Autoignition Temperature: No information available
Explosion Limits
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No information available
Specific Hazards Arising from the Chemical:
Flammable. Containers may explode when heated. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Do not allow run-off from fire fighting to enter drains or water courses.
Hazardous Combustion Products:
None known
Protective Equipment and Precautions for Firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA:
Health
3
Flammability
2
Instability
0
Physical hazards
-

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal Precautions:
Ensure adequate ventilation. Use personal protective equipment. Remove all sources of ignition. Take precautionary measures against static discharges.
Environmental Precautions:
Do not flush into surface water or sanitary sewer system. Do not allow material to contaminate ground water system. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained.
Methods for Containment and Clean Up:
Soak up with inert absorbent material. Keep in suitable, closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment.

SECTION 7. HANDLING AND STORAGE

Handling:
Wear personal protective equipment. Ensure adequate ventilation. Do not get in eyes, on skin, or on clothing. Avoid ingestion and inhalation. Keep away from open flames, hot surfaces and sources of ignition. Use only non-sparking tools. Take precautionary measures against static discharges.
Storage:
Store under an inert atmosphere. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure Guidelines
Component: Lead naphthenate
ACGIH TLV:
OSHA PEL:
NIOSH IDLH: IDLH: 100 mg/m3 TWA: 0.050 mg/m3
Mexico OEL (TWA):
Component: Stoddard solvent
ACGIH TLV: TWA: 100 ppm
OSHA PEL: (Vacated) TWA: 100 ppm; (Vacated) TWA: 525 mg/m3; TWA: 500 ppm; TWA: 2900 mg/m3
NIOSH IDLH: IDLH: 20000 mg/m3 TWA: 350 mg/m3 Ceiling: 1800 mg/m3
Mexico OEL (TWA): TWA: 100 ppm; TWA: 523 mg/m3 STEL: 200 ppm; STEL: 1050 mg/m3
Engineering Measures:
Ensure adequate ventilation, especially in confined areas. Use explosion-proof electrical/ventilating/lighting/equipment.
Personal Protective Equipment
Eye/face Protection:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection:
Long sleeved clothing.
Respiratory Protection: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Hygiene Measures:
Handle in accordance with good industrial hygiene and safety practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid
Appearance Brown
Odor oily
Odor Threshold No information available
pH No information available
Melting Point/Range No data available
Boiling Point/Range No information available
Flash Point 40 °C / 104 °F
Evaporation Rate No information available
Flammability (solid,gas) Not applicable
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density No information available
Specific Gravity 1.13 g/cm3
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature No information available
Decomposition Temperature No information available
Viscosity No information available

SECTION 10. STABILITY AND REACTIVITY

Reactive Hazard:
None known, based on information available
Stability:
Air sensitive.
Conditions to Avoid:
Keep away from open flames, hot surfaces and sources of ignition.
Incompatible Materials:
Strong oxidizing agents
Hazardous Decomposition Products:
None under normal use conditions
Hazardous Polymerization:
Hazardous polymerization does not occur.
Hazardous Reactions:
None under normal processing.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity
Product Information
Oral LD50 Category 4. ATE = 300 - 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Vapor LC50 Category 4. ATE = 10 - 20 mg/l.
Toxicologically Synergistic Products: No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation: No information available
Sensitization: No information available
Carcinogenicity:
Component / CAS-No: Lead naphthenate / 61790-14-5
IARC: Not listed
NTP: Reasonably Anticipated
ACGIH: Not listed
OSHA: X
Mexico: Not listed
Component / CAS-No: Stoddard solvent / 8052-41-3
IARC: Not listed
NTP: Not listed
ACGIH: Not listed
OSHA: Not listed
Mexico: Not listed
Mutagenic Effects: No information available
Reproductive Effects: No information available.
Developmental Effects: No information available.
Teratogenicity: No information available.
STOT - single exposure None known
STOT - repeated exposure None known
Aspiration hazard: No information available
Symptoms / effects,both acute and delayed:
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting
Endocrine Disruptor Information:
No information available
Other Adverse Effects:
The toxicological properties have not been fully investigated.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity:
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product contains following substances which are hazardous for the environment.
Persistence and Degradability: Immiscible with water
Bioaccumulation/ Accumulation: No information available.
Mobility: Is not likely mobile in the environment due its low water solubility.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods:
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.

SECTION 14. TRANSPORT INFORMATION

DOT
UN-No UN1993
Proper Shipping Name FLAMMABLE LIQUID, N.O.S. Proper technical name (lead naphthenate in mineral spirits)
Hazard Class 3
Packing Group III
TDG
UN-No UN1993
Proper Shipping Name FLAMMABLE LIQUID, N.O.S. Hazard Class 3
Packing Group III
IATA
UN-No UN1993
Proper Shipping Name FLAMMABLE LIQUID, N.O.S. Hazard Class 3
Packing Group III
IMDG/IMO
UN-No UN1993
Proper Shipping Name Flammable liquid, n.o.s. Hazard Class 3
Packing Group III

SECTION 15. REGULATORY INFORMATION

U.S. Federal Regulations
TSCA 12(b): Not applicable
SARA 313
Component: Lead naphthenate
CAS-No: 61790-14-5
Weight: 61.00 %
SARA 313 - Threshold Values: 1.0 %
CWA (Clean Water Act)
Component: Lead naphthenate
CWA - Hazardous Substances: -
CWA - Reportable Quantities: -
CWA - Toxic Pollutants: X
CWA - Priority Pollutant: -
Clean Air Act
Component: Lead naphthenate
HAPS Data: X
Class 1 Ozone Depletors:
Class 2 Ozone Depletors:
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland Security:
This product does not contain any DHS chemicals.