SECTION 1. IDENTIFICATION
Product Name: Manganese Carbide Mn23C6
Product Number: All applicable American Elements product codes, e.g. MN-C-02
, MN-C-03
, MN-C-04
, MN-C-05
CAS #: 12266-65-8
Relevant identified uses of the substance: Scientific research and development
Supplier details:
American Elements
10884 Weyburn Ave.
Los Angeles, CA 90024
Tel: +1 310-208-0551
Fax: +1 310-208-0351
Emergency telephone number:
Domestic, North America: +1 800-424-9300
International: +1 703-527-3887
SECTION 2. HAZARDS IDENTIFICATION
Classification
This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200)
Flammable solids Category 2
Serious Eye Damage/Eye Irritation Category 2
Label Elements
Signal Word:
Warning
Hazard Statements:
Flammable solid
Causes serious eye irritation
Precautionary Statements
Prevention:
Wash face, hands and any exposed skin thoroughly after handling
Keep away from heat/sparks/open flames/hot surfaces. - No smoking
Ground/bond container and receiving equipment
Use explosion-proof electrical/ventilating/lighting/equipment
Wear protective gloves/protective clothing/eye protection/face protection
Eyes:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention
Fire:
In case of fire: Use CO2, dry chemical, or foam for extinction
Hazards not otherwise classified (HNOC)
None identified
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Component:
Manganese 7439-96-5
Carbon 7440-44-0
SECTION 4. FIRST AID MEASURES
Eye Contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention.
Skin Contact:
Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Obtain medical attention.
Inhalation:
Remove from exposure, lie down. Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Obtain medical attention.
Ingestion:
Clean mouth with water. Get medical attention.
Most important symptoms and effects:
No information available.
Notes to Physician:
Treat symptomatically
SECTION 5. FIREFIGHTING MEASURES
Suitable Extinguishing Media: Dry chemical.
Unsuitable Extinguishing: Media No information available
Flash Point No information available
Method - No information available
Autoignition Temperature
Explosion Limits:
Upper No data available
Lower No data available
Sensitivity to Mechanical Impact No information available
Sensitivity to Static Discharge No
Specific Hazards Arising from the Chemical:
Combustible material
Hazardous Combustion Products:
None known
Protective Equipment and Precautions for Firefighters:
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA
Health
2
Flammability
2
Instability
0
Physical hazards
N/A
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Ensure adequate ventilation. Use personal protective equipment.
Environmental Precautions: See Section 12 for additional ecological information.
Methods for Containment and Clean Up:
Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Sweep up or vacuum up spillage and collect in suitable container for disposal.
SECTION 7. HANDLING AND STORAGE
Handling:
Avoid contact with skin and eyes. Do not breathe dust. Use explosion-proof equipment. Use only non-sparking tools.
Storage:
Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat and sources of ignition. Keep under nitrogen.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
ACGIH TLV:
TWA: 0.02 mg/m3 TWA: 0.1 mg/m3
OSHA PEL:
(Vacated) TWA: 1 mg/m3 Ceiling: 5 mg/m3
(Vacated) STEL: 3 mg/m3
(Vacated) Ceiling: 5 mg/m3
NIOSH IDLH:
IDLH: 500 mg/m3 TWA: 1 mg/m3 STEL: 3 mg/m3
Mexico OEL (TWA):
TWA: 0.2 mg/m3 TWA: 1 mg/m3 STEL: 3 mg/m3
Engineering Measures:
Ensure adequate ventilation, especially in confined areas.
Personal Protective Equipment
Eye/face Protection:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection:
Wear appropriate protective gloves and clothing to prevent skin exposure.
Respiratory Protection:
No protective equipment is needed under normal use conditions.
Hygiene Measures:
Handle in accordance with good industrial hygiene and safety practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State No information available
Appearance No information available
Odor No information available
Odor Threshold No information available
pH No information available
Melting Point/Range No information available
Boiling Point/Range No information available
Flash Point No information available
Evaporation Rate Not applicable
Flammability (solid,gas) No information available
Flammability or explosive limits
Upper No data available
Lower No data available
Vapor Pressure No information available
Vapor Density Not applicable
Specific Gravity No information available
Solubility No information available
Partition coefficient; n-octanol/water No data available
Autoignition Temperature
Decomposition Temperature No information available
Viscosity Not applicable
Molecular Formula Mn3C
Molecular Weight No information available
SECTION 10. STABILITY AND REACTIVITY
Reactive Hazard: None known, based on information available
Stability: Moisture sensitive.
Conditions to Avoid: Incompatible products. Exposure to moisture.
Incompatible Materials: Acids, Bases, Halogens
Hazardous Decomposition Products: None under normal use conditions
Hazardous Polymerization: Hazardous polymerization does not occur.
Hazardous Reactions: None under normal processing.
SECTION 11. TOXICOLOGICAL INFORMATION
Acute Toxicity
Product Information:
Component Information:
Component LD50 Oral LD50 Dermal LC50 Inhalation
Manganese LD50 = 9 g/kg ( Rat ) Not listed Not listed
Toxicologically Synergistic Products
No information available
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Irritation No information available
Sensitization No information available
Carcinogenicity
IARC: Not listed
NTP: Not listed
ACGIH: Not listed
OSHA: Not listed
Mexico: Not listed
Mutagenic Effects No information available
Reproductive Effects No information available.
Developmental Effects No information available.
Teratogenicity No information available.
STOT - single exposure None known
STOT - repeated exposure None known
Aspiration hazard No information available
Symptoms / effects,both acute and delayed
No information available
Endocrine Disruptor Information
No information available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Do not empty into drains.
Persistence and Degradability:
Insoluble in water
Bioaccumulation/ Accumulation:
No information available.
Mobility:
Is not likely mobile in the environment due its low water solubility.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste Disposal Methods:
Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification.
SECTION 14. TRANSPORT INFORMATION
DOT
UN-No UN3089
Hazard Class 4.1
Packing Group III
TDG
UN-No UN3089
Hazard Class 4.1
Packing Group III
IATA
UN-No 3089
Proper Shipping Name METAL POWDER, FLAMMABLE, N.O.S. Hazard Class 4.1
Packing Group III
IMDG/IMO
UN-No 3089
Proper Shipping Name METAL POWDER, FLAMMABLE, N.O.S. Hazard Class 4.1
Packing Group III
1
SECTION 15. REGULATORY INFORMATION
TSCA: X
DSL: X
NDSL: -
EINECS: 231-105-1
ELINCS: -
NLP
PICCS: X
ENCS: -
AICS: X
IECSC: X
KECL: X
U.S. Federal Regulations
TSCA 12(b) Not applicable
CWA (Clean Water Act) Not applicable
Clean Air Act
HAPS Data: X
Class 1 Ozone Depletors
Class 2 Ozone Depletors: -
OSHA:
Not applicable
CERCLA Not applicable
California Proposition 65 This product does not contain any Proposition 65 chemicals
U.S. State Right-to-Know Regulations
Component; Manganese
Massachusetts: X
New Jersey: X
Pennsylvania: X
Illinois: X
Rhode Island: X
U.S. Department of Transportation
Reportable Quantity (RQ): N
DOT Marine Pollutant N
DOT Severe Marine Pollutant N
U.S. Department of Homeland Security
This product does not contain any DHS chemicals.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. COPYRIGHT 1997-2022 AMERICAN ELEMENTS. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY.
The number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. 
It is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."