SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
GHS02 Flame
Flam. Liq. 3 H226 Flammable liquid and vapor.
GHS08 Health hazard
Repr. 1A H360 May damage fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
GHS07
Acute Tox. 4 H302 Harmful if swallowed.
Acute Tox. 4 H332 Harmful if inhaled.
· Label elements
· GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictogram
· Signal word Danger
· Hazard statements
H226 Flammable liquid and vapor.
H302+H332 Harmful if swallowed or if inhaled.
H360 May damage fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
· Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P281 Use personal protective equipment as required.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Classification system:
· NFPA ratings (scale 0 - 4)
Health = 4
Fire = 2
Reactivity = 0
· HMIS-ratings (scale 0 - 4)
Health = 4
Fire = 2
Reactivity = 0
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Substances
· CAS No. Description
69507-98-8 Methylammonium triiodoplumbate(II) (40wt% solution in DMF)
SECTION 4. FIRST AID MEASURES
Description of first aid measures
· General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
· After inhalation:
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
· After skin contact: Immediately rinse with water.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Immediately call a doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5. FIREFIGHTING MEASURES
· Extinguishing media
· Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: Mouth respiratory protective device.
SECTION 6. ACCIDENTAL RELEASE MEASURES
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
· Environmental precautions:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7. HANDLING AND STORAGE
· Handling:
· Precautions for safe handling
Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
Open and handle receptacle with care.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Keep receptacle tightly sealed.
· Specific end use(s) No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace: Not required.
· Additional information: The lists that were valid during the creation were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air.
· Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection:
Tightly sealed goggles
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Liquid
Color: Yellow
· Odor: undistinguishable
· Odor threshold: Not determined.
· pH-value: Not applicable.
· Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
· Flash point: 60 °C (140 °F)
· Flammability (solid, gaseous): Flammable.
· Ignition temperature:
Decomposition temperature: Not determined.
· Auto igniting: Not determined.
· Danger of explosion: Not determined.
· Explosion limits:
Lower: Not determined.
Upper: Not determined.
· Vapor pressure: Not applicable.
· Density at 20 °C (68 °F): 1.368 g/cm³ (11.416 lbs/gal)
· Relative density Not determined.
· Vapor density Not applicable.
· Evaporation rate Not applicable.
· Solubility in / Miscibility with
Water: Insoluble.
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
· Solvent content:
Organic solvents: 0.0 %
VOC content: 0.0 g/l / 0.00 lb/gl
Solids content: 100.0 %
· Other information No further relevant information available.
SECTION 10. STABILITY AND REACTIVITY
· Reactivity No further relevant information available.
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: No dangerous decomposition products known.
SECTION 11. TOXICOLOGICAL INFORMATION
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
· Additional toxicological information:
· Carcinogenic categories
· IARC (International Agency for Research on Cancer)
Substance is not listed.
· NTP (National Toxicology Program)
Substance is not listed.
· OSHA-Ca (Occupational Safety & Health Administration)
Substance is not listed.
SECTION 12. ECOLOGICAL INFORMATION
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behavior in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
· Waste treatment methods
· Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
· UN-Number
· DOT, IMDG, IATA UN2929
· UN proper shipping name
· DOT, IATA Toxic liquids, flammable, organic, n.o.s.
· IMDG TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S.
· Transport hazard class(es)
· DOT
· Class 6.1 Toxic substances
· Label 6.1, 3
· IMDG
· Class 6
· Label 6.1/3
· IATA
· Class 6.1 Toxic substances
· Label 6.1 (3)
· Packing group
· DOT, IMDG, IATA I
· Environmental hazards: Not applicable.
· Special precautions for user Not applicable.
· EMS Number: F-E,S-D
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information:
· DOT
· Quantity limitations On passenger aircraft/rail: 1 L
On cargo aircraft only: 30 L
· IMDG
· Limited quantities (LQ) 0
· Excepted quantities (EQ) Code: E5
Maximum net quantity per inner packaging: 1 g
Maximum net quantity per outer packaging: 300 g
· UN "Model Regulation": UN 2929 TOXIC LIQUIDS, FLAMMABLE, ORGANIC, N.O.S., 6.1 (3), I
SECTION 15. REGULATORY INFORMATION
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· Sara
· Section 355 (extremely hazardous substances):
Substance is not listed.
· Section 313 (Specific toxic chemical listings):
Substance is not listed.
· TSCA (Toxic Substances Control Act):
Substance is not listed.
· Proposition 65
· Chemicals known to cause cancer:
Substance is not listed.
· Chemicals known to cause reproductive toxicity for females:
Substance is not listed.
· Chemicals known to cause reproductive toxicity for males:
Substance is not listed.
· Chemicals known to cause developmental toxicity:
Substance is not listed.
· Carcinogenic categories
· EPA (Environmental Protection Agency)
Substance is not listed.
· TLV (Threshold Limit Value established by ACGIH)
Substance is not listed.
· NIOSH-Ca (National Institute for Occupational Safety and Health)
Substance is not listed.
· GHS label elements
The substance is classified and labeled according to the Globally Harmonized System (GHS).
· Hazard pictograms
GHS02 GHS07 GHS08
· Signal word Danger
· Hazard statements
H226 Flammable liquid and vapor.
H302+H332 Harmful if swallowed or if inhaled.
H360 May damage fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
· Precautionary statements
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P281 Use personal protective equipment as required.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· National regulations:
· Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
