Microscopic evidence for humic acid induced changes in lead immobilization by phosphate in a counterdiffusion system.

Title Microscopic evidence for humic acid induced changes in lead immobilization by phosphate in a counterdiffusion system.
Authors M. Wang; Z. Zhang; J. Ren; C. Zhang; C. Li; G. Guo; F. Li
Journal J Hazard Mater
DOI 10.1016/j.jhazmat.2017.02.008
Abstract

Abatement of lead (Pb) contamination in soil via chemical immobilization can reduce potential risks but is influenced by soil organic matter. The aim of this study was to observe and understand the influence of organic matter on Pb immobilization by phosphate. For this purpose, humic acid (HA) was introduced into a counterdiffusion system to mimic ionic reactions of the mineralization processes between the pollutant (Pb) and amendment agent (phosphate) in soil system, and were characterized jointly by in situ optical microscopy and ex situ XRD, SEM, TEM, and LSCM. The results indicate that lead immobilization in the counterdiffusion system involves a time-dependent crystallization process and that supersaturation occurs at nearly central region of the reaction zone. Entrapped HA had influence on crystal growth and size, causing more fragmented crystal morphology with increasing HA content, which can be explained by HA wrapping of the nucleation products and subsequent inhibition of reactions and crystal growth, as indicated by TEM and LSCM images. Mineral conversion from secondary lead orthophosphates to pyromorphite implies the promotion of more stable minerals. This approach provides evidence for a more intuitive understanding of the effects of HA on the immobilization of lead by phosphates.

Citation M. Wang; Z. Zhang; J. Ren; C. Zhang; C. Li; G. Guo; F. Li.Microscopic evidence for humic acid induced changes in lead immobilization by phosphate in a counterdiffusion system.. J Hazard Mater. 2017;330:4651. doi:10.1016/j.jhazmat.2017.02.008

Related Elements

Phosphorus

Phosphorus Bohr ModelSee more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.

Lead

Lead Bohr ModelSee more Lead products. Lead (atomic symbol: Pb, atomic number: 82) is a Block P, Group 14, Period 6 element with an atomic radius of 207.2. The number of electrons in each of Lead's shells is [2, 8, 18, 32, 18, 4] and its electron configuration is [Xe] 4f14 5d10 6s2 6p2. The lead atom has a radius of 175 pm and a Van der Waals radius of 202 pm. In its elemental form, lead has a metallic gray appearance. Lead occurs naturally as a mixture of four stable isotopes: 204Pb (1.48%), 206Pb (23.6%), 207Pb (22.6%), and 208Pb (52.3%). Elemental LeadLead is obtained mainly from galena (PbS) by a roasting process. Anglesite, cerussite, and minim are other common lead containing minerals. Lead does occur as a free element in nature, but it is rare. It is a dense, soft metal that is very resistant to corrosion and poorly conductive compared to other metals. Its density and low melting point make it useful in applications such as electrolysis and industrial materials.

Related Forms & Applications