Na(UO)(BO): An All-Uranium(V) Borate Synthesized under Mild Hydrothermal Conditions.

Title Na(UO)(BO): An All-Uranium(V) Borate Synthesized under Mild Hydrothermal Conditions.
Authors K.A. Pace; V. Kocevski; S.G. Karakalos; G. Morrison; T. Besmann; H.Czur Loye
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.8b00487
Abstract

The first entirely pentavalent uranium borate, Na(UO)(BO), was synthesized under mild hydrothermal conditions. The single-crystal structure was solved in the orthorhombic space group Cmcm with a = 10.0472(3) Å, b = 6.5942(2) Å, and c = 6.9569(2) Å. Magnetic susceptibility measurements revealed an antiferromagnetic transition at 12 K and an effective magnetic moment of 2.33 ?. Density functional theory calculations indicated dynamic stability of the structure above 0 K.

Citation K.A. Pace; V. Kocevski; S.G. Karakalos; G. Morrison; T. Besmann; H.Czur Loye.Na(UO)(BO): An All-Uranium(V) Borate Synthesized under Mild Hydrothermal Conditions.. Inorg Chem. 2018;57(8):42444247. doi:10.1021/acs.inorgchem.8b00487

Related Elements

Boron

See more Boron products. Boron Bohr ModelBoron (atomic symbol: B, atomic number: 5) is a Block P, Group 13, Period 2 element with an atomic weight of 10.81. The number of electrons in each of boron's shells is 2, 3 and its electron configuration is [He] 2s2 2p1. The boron atom has a radius of 90 pm and a Van der Waals radius of 192 pm. Boron was discovered by Joseph Louis Gay-Lussac and Louis Jacques Thénard in 1808 and was first isolated by Humphry Davy later that year. Boron is classified as a metalloid is not found naturally on earth. Elemental BoronAlong with carbon and nitrogen, boron is one of the few elements in the periodic table known to form stable compounds featuring triple bonds. Boron has an energy band gap of 1.50 to 1.56 eV, which is higher than that of either silicon or germanium. The name Boron originates from a combination of carbon and the Arabic word buraqu meaning borax.

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