New rare earth hafnium oxynitride perovskites with photocatalytic activity in water oxidation and reduction.

Title New rare earth hafnium oxynitride perovskites with photocatalytic activity in water oxidation and reduction.
Authors A.P. Black; H. Suzuki; M. Higashi; C. Frontera; C. Ritter; C. De; A. Sundaresan; R. Abe; A. Fuertes
Journal Chem Commun (Camb)
DOI 10.1039/c7cc08965a
Abstract

RHfO2N perovskites with R = La, Nd and Sm show a GdFeO3-type structure and are semiconductors with band gaps of 3.35, 3.40 and 2.85 eV and relative dielectric constants of 30, 16 and 28 respectively. These compounds have adequate reduction and oxidation potentials to conduct the overall water splitting reaction, and the analogous perovskite LaZrO2N with a band gap of 2.8 eV shows photocatalytic activity under visible light irradiation for O2 evolution.

Citation A.P. Black; H. Suzuki; M. Higashi; C. Frontera; C. Ritter; C. De; A. Sundaresan; R. Abe; A. Fuertes.New rare earth hafnium oxynitride perovskites with photocatalytic activity in water oxidation and reduction.. Chem Commun (Camb). 2018;54(12):15251528. doi:10.1039/c7cc08965a

Related Elements

Hafnium

See more Hafnium products. Hafnium (atomic symbol: Hf, atomic number: 72) is a Block D, Group 4, Period 6 element with an atomic weight of 178.49. Hafnium Bohr ModelThe number of electrons in each of Hafnium's shells is 2, 8, 18, 32, 10, 2 and its electron configuration is [Xe] 4f14 5d2 6s2. The hafnium atom has a radius of 159 pm and a Van der Waals radius of 212 pm. Hafnium was predicted by Dmitri Mendeleev in 1869 but it was not until 1922 that it was first isolated Dirk Coster and George de Hevesy. In its elemental form, hafnium has a lustrous silvery-gray appearance. Elemental HafniumHafnium does not exist as a free element in nature. It is found in zirconium compounds such as zircon. Hafnium is often a component of superalloys and circuits used in semiconductor device fabrication. Its name is derived from the Latin word Hafnia, meaning Copenhagen, where it was discovered.

Nitrogen

See more Nitrogen products. Nitrogen is a Block P, Group 15, Period 2 element. Its electron configuration is [He]2s22p3. Nitrogen is an odorless, tasteless, colorless and mostly inert gas. It is the seventh most abundant element in the universe and it constitutes 78.09% (by volume) of Earth's atmosphere. Nitrogen was discovered by Daniel Rutherford in 1772.

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