Nitrogen-doped carbon quantum dots as fluorescent probe for "off-on" detection of mercury ions, l-cysteine and iodide ions.

Title Nitrogen-doped carbon quantum dots as fluorescent probe for "off-on" detection of mercury ions, l-cysteine and iodide ions.
Authors H. Huang; Y. Weng; L. Zheng; B. Yao; W. Weng; X. Lin
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2017.07.076
Abstract

The application of fluorescent nanoparticles to the detection of inorganic ions and organic compounds has been attracted wide attention recently. In this paper, an "off-on" method for highly sensitive and selective detection of Hg(2+) and l-cysteine (l-Cys) or Hg(2+) and I(-) using home-made nitrogen-doped carbon quantum dots (N-CQDs) as fluorescent probe was reported. The N-CQDs with a fluorescence quantum yield of 42.2% were prepared using tartaric acid, citric acid and ethanediamine as the precursors in the oleic acid media. The fluorescence of the obtained N-CQDs could be quenched selectively and sensitively by the addition of Hg(2+) (turn-off) with a detection limit of 83.5nM. When l-Cys or I(-) was added into the N-CQDs-Hg(2+) system, the fluorescence was recovered effectively (turn-on). This process could be used to the detection of l-Cys or I(-) with a detection limit of 45.8 and 92.3nM, respectively.

Citation H. Huang; Y. Weng; L. Zheng; B. Yao; W. Weng; X. Lin.Nitrogen-doped carbon quantum dots as fluorescent probe for "off-on" detection of mercury ions, l-cysteine and iodide ions.. J Colloid Interface Sci. 2017;506:373378. doi:10.1016/j.jcis.2017.07.076

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See more Carbon products. Carbon (atomic symbol: C, atomic number: 6) is a Block P, Group 14, Period 2 element. Carbon Bohr ModelThe number of electrons in each of Carbon's shells is 2, 4 and its electron configuration is [He]2s2 2p2. In its elemental form, carbon can take various physical forms (known as allotropes) based on the type of bonds between carbon atoms; the most well known allotropes are diamond, graphite, amorphous carbon, glassy carbon, and nanostructured forms such as carbon nanotubes, fullerenes, and nanofibers . Carbon is at the same time one of the softest (as graphite) and hardest (as diamond) materials found in nature. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element (by mass) in the universe after hydrogen, helium, and oxygen. Carbon was discovered by the Egyptians and Sumerians circa 3750 BC. It was first recognized as an element by Antoine Lavoisier in 1789.

Mercury

Mercury Bohr ModelSee more Mercury products. Mercury (atomic symbol: Hg, atomic number: 80) is a Block D, Group 12, Period 6 element with an atomic weight of 200.59. The number of electrons in each of mercury's shells is 2, 8, 18,32, 18, 2 and its electron configuration is [Xe] 4f14 5d10 6s2. The mercury atom has a radius of 151 pm and a Van der Waals radius of 209 pm. It is named after the planet Mercury and often referred to as "quicksilver" due to its appearance as a silvery liquid. Mercury has low melting and boiling points. It is a poor conductor of heat, but a fair conductor of electricity. Mercury is found both as a free element and in cinnabar, corderoite, and livingstonite ores.

Iodine

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