Optical spectroscopy, 1.06?m emission properties of Nd(3+)-doped phosphate based glasses.

Title Optical spectroscopy, 1.06?m emission properties of Nd(3+)-doped phosphate based glasses.
Authors R.Sk Nayab; S. T; M.Babu A; R.Moorthy L; J.C. K
Journal Spectrochim Acta A Mol Biomol Spectrosc
DOI 10.1016/j.saa.2017.03.012
Abstract

Neodymium doped phosphate based glasses with composition of (P2O5+K2O+Al2O3+CaF2) were prepared. The samples were analysed through differential thermal analysis (DTA), Fourier transform infrared (FTIR), absorption, emission and decay measurements. Judd-Ofelt parameters (??) have been determined from the spectral intensities of absorption bands in order to calculate the radiative parameters like radiative transition probabilities (AR), radiative lifetime (?R) and branching ratios (?R) for the (4)F3/2?(4)I11/2 laser transition of Nd(3+) ion. The effective emission bandwidths (??eff), experimental branching ratios (?exp) and stimulated emission cross-sections (?e) have been determined from the emission spectrum. The decay curves of the (4)F3/2 level exhibited almost single exponential nature for all the Nd(3+) ion concentrations.

Citation R.Sk Nayab; S. T; M.Babu A; R.Moorthy L; J.C. K.Optical spectroscopy, 1.06?m emission properties of Nd(3+)-doped phosphate based glasses.. Spectrochim Acta A Mol Biomol Spectrosc. 2017;180:193197. doi:10.1016/j.saa.2017.03.012

Related Elements

Phosphorus

Phosphorus Bohr ModelSee more Phosphorus products. Phosphorus (atomic symbol: P, atomic number: 15) is a Block P, Group 15, Period 3 element. The number of electrons in each of Phosphorus's shells is 2, 8, 5 and its electronic configuration is [Ne] 3s2 3p3. The phosphorus atom has a radius of 110.5.pm and its Van der Waals radius is 180.pm. Phosphorus is a highly-reactive non-metallic element (sometimes considered a metalloid) with two primary allotropes, white phosphorus and red phosphorus its black flaky appearance is similar to graphitic carbon. Compound forms of phosphorus include phosphates and phosphides. Phosphorous was first recognized as an element by Hennig Brand in 1669 its name (phosphorus mirabilis, or "bearer of light") was inspired from the brilliant glow emitted by its distillation.

Neodymium

See more Neodymium products. Neodymium (atomic symbol: Nd, atomic number: 60)is a Block F, Group 3, Period 6 element with an atomic weight of 144.242. Neodymium Bohr ModelThe number of electrons in each of Neodymium's shells is 2, 8, 18, 22, 8, 2 and its electron configuration is [Xe] 4f4 6s2. The neodymium atom has a radius of 181 pm and a Van der Waals radius of 229 pm. Neodymium was first discovered by Carl Aer von Welsbach in 1885. In its elemental form, neodymium has a silvery-white appearance. Neodymium is the most abundant of the rare earths after cerium and lanthanum. Neodymium is found in monazite and bastnäsite ores. It is used to make high-strength neodymium magnets and laser crystal substances like neodymium-doped yttrium aluminum garnet (also known as Nd:YAG). The name originates from the Greek words neos didymos, meaning new twin.

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