Organophosphonate-Bridged Polyoxometalate-Based Dysprosium(III) Single-Molecule Magnet.

Title Organophosphonate-Bridged Polyoxometalate-Based Dysprosium(III) Single-Molecule Magnet.
Authors Y. Huo; R. Wan; P. Ma; J. Liu; Y. Chen; D. Li; J. Niu; J. Wang; M.L. Tong
Journal Inorg Chem
DOI 10.1021/acs.inorgchem.7b02251
Abstract

A novel dysprosium(III)-containing polytungstoarsenate, [{(AsW9O33)3Dy2(H2O)4W4O9(H2O)}2(NH2(CH2PO3)2)]33-, comprising two identical subunits bridged by an organophosphonate ligand shows single-molecule-magnet (SMM) behavior. Magnetic studies reveal that this complex exhibits a butterfly-shaped hysteresis loop up to 8 K, and a thermally activated energy barrier of 101(5) K reached a breakthrough among all polyoxometalate-supported SMMs.

Citation Y. Huo; R. Wan; P. Ma; J. Liu; Y. Chen; D. Li; J. Niu; J. Wang; M.L. Tong.Organophosphonate-Bridged Polyoxometalate-Based Dysprosium(III) Single-Molecule Magnet.. Inorg Chem. 2017;56(21):1268712691. doi:10.1021/acs.inorgchem.7b02251

Related Elements

Dysprosium

See more Dysprosium products. Dysprosium (atomic symbol: Dy, atomic number: 66) is a Block F, Group 3, Period 6 element with an atomic radius of 162.5. Dysprosium Bohr ModelThe number of electrons in each of dysprosium's shells is [2, 8, 18, 28, 8, 2] and its electron configuration is [Xe]4f10 6s2. The dysprosium atom has an atomic radius of 178 pm and a Van der Waals radius of 229 pm. Dysprosium was first discovered by Paul Emile Lecoq de Boisbaudran in 1886. In its elemental form, dysprosium has a silvery-white appearance. Elemental Dysprosium PictureIt is a member of the lanthanide or rare earth series of elements and, along with holmium, has the highest magnetic strength of all other elements on the periodic table, especially at low temperatures. Dysprosium is found in various minerals including bastnäsite, blomstrandine, euxenite, fergusonite, gadolinite, monazite, polycrase and xenotime. It is not found in nature as a free element. The element name originates from the Greek word dysprositos, meaning hard to get at.

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