pH-dependent synthesis of iodine-deficient bismuth oxyiodide microstructures: Visible-light photocatalytic activity.

Title pH-dependent synthesis of iodine-deficient bismuth oxyiodide microstructures: Visible-light photocatalytic activity.
Authors G. Wu; Y. Zhao; Y. Li; H. Ma; J. Zhao
Journal J Colloid Interface Sci
DOI 10.1016/j.jcis.2017.09.053
Abstract

Bismuth oxyiodides have exhibited high potential for applications in visible-light photocatalytic environmental remediation and solar energy conversion. In this work, a series of iodine-deficient bismuth oxyiodides (Bi4O5I2, Bi7O9I3, Bi5O7I) can be simply prepared through a pH-dependent aqueous procedure with feeding Bi/I ratio of 2:1. The compositions of the Bi-based oxyiodides are closely related to acid-base circumstances, with Bi4O5I2 formed in weakly acidic medium (pH = 5) and Bi7O9I3, Bi5O7I in basic medium (pH = 8 and 11). Morphology differences of nanosheet-assembled Bi4O5I2, Bi7O9I3 architectures and rod-like Bi5O7I microstructures demonstrate different crystalline characters and construction of Bi-based oxyiodide crystals. UV-vis DRS results revealed good visible-light absorptions of Bi4O5I2 and Bi7O9I3 architectures and appropriate band structures for photocatalytic reactions, on comparison to Bi5O7I microrods. Low electrochemical impedance of Bi7O9I3 microflowers with sheet-like units further facilitated the separation of e--h+ carriers in the degradation process. Accordingly, among the bismuth oxyiodide samples, Bi7O9I3 displayed prominent visible-light degradation performance for colorless bisphenol-A (BPA) due to the direct photoexcitation process.

Citation G. Wu; Y. Zhao; Y. Li; H. Ma; J. Zhao.pH-dependent synthesis of iodine-deficient bismuth oxyiodide microstructures: Visible-light photocatalytic activity.. J Colloid Interface Sci. 2018;510:228236. doi:10.1016/j.jcis.2017.09.053

Related Elements

Bismuth

See more Bismuth products. Bismuth (atomic symbol: Bi, atomic number: 83) is a Block P, Group 15, Period 6 element with an atomic radius of 208.98040. The number of electrons in each of Bismuth's shells is 2, 8, 18, 32, 18, 5 and its electron configuration is [Xe] 4f14 5d10 6s2 6p3. Bismuth Bohr ModelThe bismuth atom has a radius of 156 pm and a Van der Waals radius of 207 pm. In its elemental form, bismuth is a silvery white brittle metal. Bismuth is the most diamagnetic of all metals and, with the exception of mercury, its thermal conductivity is lower than any other metal. Elemental BismuthBismuth has a high electrical resistance, and has the highest Hall Effect of any metal (i.e., greatest increase in electrical resistance when placed in a magnetic field). Bismuth is found in bismuthinite and bismite. It is also produced as a byproduct of lead, copper, tin, molybdenum and tungsten extraction. Bismuth was first discovered by Early Man. The name Bismuth originates from the German word 'wissmuth,' meaning white mass.

Iodine

See more Iodine products. Iodine (atomic symbol: I, atomic number: 53) is a Block P, Group 17, Period 5 element with an atomic radius of 126.90447. The number of electrons in each of Iodine's shells is 2, 8, 18, 18, 7 and its electron configuration is [Kr] 4d10 5s2 5p5. The iodine atom has a radius of 140 pm and a Van der Waals radius of 198 pm. In its elemental form, iodine has a lustrous metallic gray appearance as a solid and a violet appearance as a gas or liquid solution. Elemental IodineIodine forms compounds with many elements, but is less active than the other halogens. It dissolves readily in chloroform, carbon tetrachloride, or carbon disulfide. Iodine compounds are important in organic chemistry and very useful in the field of medicine. Iodine was discovered and first isolated by Bernard Courtois in 1811. The name Iodine is derived from the Greek word "iodes" meaning violet.

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