Polyoxometalate-Based Bottom-Up Fabrication of Graphene Quantum Dot/Manganese Vanadate Composites as Lithium Ion Battery Anodes.

Title Polyoxometalate-Based Bottom-Up Fabrication of Graphene Quantum Dot/Manganese Vanadate Composites as Lithium Ion Battery Anodes.
Authors Y. Ji; J. Hu; J. Biskupek; U. Kaiser; Y.F. Song; C. Streb
Journal Chemistry
DOI 10.1002/chem.201703851
Abstract

Lithium ion battery (LIB) electrodes require a stable connection between a redox-active metal oxide for charge storage and an electrically conductive (often carbon-based) material for charge transport. As charge transfer within the metal oxide is often a performance-limiting factor, one promising concept is the linking of charge transfer and charge storage components on the nanoscale. This would maximize the interfacial contact area and improve charging/discharging behavior. This work presents a one-step, room-temperature route giving nanostructured manganese vanadium oxide/graphene quantum dot (GQD) composite electrodes. Manganese vanadium oxide clusters are used as solution-processable precursors, which are deposited on GQDs using a sonication-driven conversion leading to electroactive, lightweight composites. Incorporation of the composites as anodes in LIBs shows high electrochemical performance featuring discharge capacities of 970?mAh?g-1 over 100?cycles with coulombic efficiencies near 100?%. The study shows how 3d-metal oxide/GQD nanostructures can be accessed by a scalable sonication route starting from soluble, chemically tunable metal oxide clusters and graphene quantum dots.

Citation Y. Ji; J. Hu; J. Biskupek; U. Kaiser; Y.F. Song; C. Streb.Polyoxometalate-Based Bottom-Up Fabrication of Graphene Quantum Dot/Manganese Vanadate Composites as Lithium Ion Battery Anodes.. Chemistry. 2017;23(65):1663716643. doi:10.1002/chem.201703851

Related Elements

Carbon

See more Carbon products. Carbon (atomic symbol: C, atomic number: 6) is a Block P, Group 14, Period 2 element. Carbon Bohr ModelThe number of electrons in each of Carbon's shells is 2, 4 and its electron configuration is [He]2s2 2p2. In its elemental form, carbon can take various physical forms (known as allotropes) based on the type of bonds between carbon atoms; the most well known allotropes are diamond, graphite, amorphous carbon, glassy carbon, and nanostructured forms such as carbon nanotubes, fullerenes, and nanofibers . Carbon is at the same time one of the softest (as graphite) and hardest (as diamond) materials found in nature. It is the 15th most abundant element in the Earth's crust, and the fourth most abundant element (by mass) in the universe after hydrogen, helium, and oxygen. Carbon was discovered by the Egyptians and Sumerians circa 3750 BC. It was first recognized as an element by Antoine Lavoisier in 1789.

Manganese

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr ModelThe number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental ManganeseIt is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

Vanadium

See more Vanadium products. Vanadium (atomic symbol: V, atomic number: 23) is a Block D, Group 5, Period 4 element with an atomic weight of 50.9415. Vanadium Bohr ModelThe number of electrons in each of Vanadium's shells is 2, 8, 11, 2 and its electron configuration is [Ar] 3d3 4s2. The vanadium atom has a radius of 134 pm and a Van der Waals radius of 179 pm. Vanadium was discovered by Andres Manuel del Rio in 1801 and first isolated by Nils Gabriel Sefström in 1830. In its elemental form, vanadium has a bluish-silver appearance. Elemental VanadiumIt is a hard, ductile transition metal that is primarily used as a steel additive and in alloys such as Titanium-6AL-4V, which is composed of titanium, aluminum, and vanadium and is the most common titanium alloy commercially produced. Vanadium is found in fossil fuel deposits and 65 different minerals. Vanadium is not found free in nature; however, once isolated it forms an oxide layer that stabilizes the free metal against further oxidation. Vanadium was named after the word "Vanadis" meaning goddess of beauty in Scandinavian mythology.

Lithium

Lithium Bohr ModelSee more Lithium products. Lithium (atomic symbol: Li, atomic number: 3) is a Block S, Group 1, Period 2 element with an atomic weight of 6.94. The number of electrons in each of Lithium's shells is [2, 1] and its electron configuration is [He] 2s1. The lithium atom has a radius of 152 pm and a Van der Waals radius of 181 pm. Lithium was discovered by Johann Arvedson in 1817 and first isolated by William Thomas Brande in 1821. The origin of the name Lithium comes from the Greek wordlithose which means "stone." Lithium is a member of the alkali group of metals. It has the highest specific heat and electrochemical potential of any element on the period table and the lowest density of any elements that are solid at room temperature. Elemental LithiumCompared to other metals, it has one of the lowest boiling points. In its elemental form, lithium is soft enough to cut with a knife its silvery white appearance quickly darkens when exposed to air. Because of its high reactivity, elemental lithium does not occur in nature. Lithium is the key component of lithium-ion battery technology, which is becoming increasingly more prevalent in electronics.

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