Prediction of isoelectric point of manganese and cobalt lamellar oxides: application to controlled synthesis of mixed oxides.

Title Prediction of isoelectric point of manganese and cobalt lamellar oxides: application to controlled synthesis of mixed oxides.
Authors C. Tang; D. Giaume; L. Guerlou-Demourgues; G. Lefèvre; P. Barboux
Journal Langmuir
DOI 10.1021/acs.langmuir.8b00190
Abstract

To design novel layered materials, bottom-up strategy is very promising. It consists in (1) synthesizing various layered oxides, (2) exfoliating them, then (3) restacking them in a controlled way. The latter step is based on electrostatic interactions between different layered oxides and is difficult to control. The aim of this study is to facilitate this step by predicting the isoelectric point (IEP) of exfoliated materials. Multisite Complexation model (MUSIC) was used in this objective and was shown to be able to predict IEP from the mean oxidation state of the metal in the (hydr)oxides, as the main parameter. Moreover, the effect of exfoliation on IEP has also been calculated: starting from platelets with a high basal/area percentage: exfoliation process has no impact on calculated IEP value, as verified on experimental values. Moreover, the restacked materials containing different monometallic (hydr)oxide layers also have an IEP consistent with values calculated with the model. This study proves that MUSIC model is a useful tool to predict IEP of various complex metal oxides and hydroxides.

Citation C. Tang; D. Giaume; L. Guerlou-Demourgues; G. Lefèvre; P. Barboux.Prediction of isoelectric point of manganese and cobalt lamellar oxides: application to controlled synthesis of mixed oxides.. Langmuir. 2018. doi:10.1021/acs.langmuir.8b00190

Related Elements

Cobalt

See more Cobalt products. Cobalt (atomic symbol: Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Cobalt Bohr ModelThe number of electrons in each of cobalt's shells is 2, 8, 15, 2 and its electron configuration is [Ar]3d7 4s2. The cobalt atom has a radius of 125 pm and a Van der Waals radius of 192 pm. Cobalt was first discovered by George Brandt in 1732. In its elemental form, cobalt has a lustrous gray appearance. Cobalt is found in cobaltite, erythrite, glaucodot and skutterudite ores. Elemental CobaltCobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and high-strength superalloys. Co-60, a commercially important radioisotope, is useful as a radioactive tracer and gamma ray source. The origin of the word Cobalt comes from the German word "Kobalt" or "Kobold," which translates as "goblin," "elf" or "evil spirit.

Manganese

See more Manganese products. Manganese (atomic symbol: Mn, atomic number: 25) is a Block D, Group 7, Period 4 element with an atomic weight of 54.938045. Manganese Bohr ModelThe number of electrons in each of Manganese's shells is [2, 8, 13, 2] and its electron configuration is [Ar] 3d5 4s2. The manganese atom has a radius of 127 pm and a Van der Waals radius of 197 pm. Manganese was first discovered by Torbern Olof Bergman in 1770 and first isolated by Johann Gottlieb Gahn in 1774. In its elemental form, manganese has a silvery metallic appearance. Elemental ManganeseIt is a paramagnetic metal that oxidizes easily in addition to being very hard and brittle. Manganese is found as a free element in nature and also in the minerals pyrolusite, braunite, psilomelane, and rhodochrosite. The name Manganese originates from the Latin word mangnes, meaning "magnet."

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